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13 Al 26.98153861(8)

Aluminum

Poor metal
Symbol Al
Atomic Number 13
Atomic Weight 26.98153861(8)
CAS Registry ID 7429-90-5
Group Name (none)
Period Number 3
Block p-block
State at STP Solid

Description

Sample of Aluminum ⌕ Enlarge Image

Aluminum is one of the poor metals that is a silver colored solid in its natural state. Aluminum has an atomic weight of 26.9815386, a melting point of 1220.58 °F, and a boiling point of 4566 °F. Aluminum is the most abundant metal in the Earth’s crust, and it is used for a variety of purposes. Some of the more common uses of aluminum include: as a powder in the composition of paints, pyrotechnics, and thermites, as a solid for construction of transportation vehicles, and in the manufacture of cooking utensils.

Isolation

Aluminum is a highly reactive metal and so it is not found free in nature. While different isolation processes are possible, only a few are used due to energy costs.

Aluminum ⌕ Enlarge Image

The largest source for aluminum that is used for large scale commercial isolation is from bauxite. Bauxite is a type of ore that is striped mined because of its large aluminum content. The process which is used to isolate aluminum from bauxite is called the Bayer process. During this process, the bauxite ore is combined with sodium hydroxide and heated under pressure to approximately 392 °F. The result is a solution which contains sodium aluminate and sodium silicate. In the next step of the Bayer process, carbon dioxide is run through the solution resulting in a precipitate of aluminum hydroxide. The aluminum hydroxide is then filtered, washed, and heated to form alumina, (Al2O3). The final step used to separate pure aluminum from alumina is performed by using electrolysis. To minimize the energy that is needed for the electrolysis step, carbon lined steel cells are used as the cathodes and anodes for this reaction.

General

NameAluminum
SymbolAl
Number13
Chemical seriesPoor metal
Group13
Period3
Blockp
Appearancesilvery
Standard atomic weight26.98153861(8) g·mol⁻¹
Electron configuration[Ne] 3s2 3p1
Electrons per shell2, 8, 3

Atomic Properties

Crystal structureface centered cubic 0.4032 nm
Oxidation states3 (amphoteric oxide)
Electronegativity1.61 (Pauling scale)
Ionization energies1st: 577.5 kJ·mol-1
2nd: 1816.7 kJ·mol-1
3rd: 2744.8 kJ·mol-1
Atomic radius125 pm
Atomic radius (calc.)118 pm
Covalent radius118 pm
Van der Waals radius

Physical Properties

Phasesolid
Density (near r.t.)2.70 g·cm-3
Liquid density at m.p.2.375 g·cm-3
Melting point933.47 K (660.32 °C, 1220.58 °F)
Boiling point2792 K (2519 °C, 4566 °F)
Critical point
Heat of fusion10.71 kJ·mol-1
Heat of vaporization294.0 kJ·mol-1
Heat capacity(25 °C) 24.200 J·mol-1·K-1

Miscellaneous

Magnetic orderingparamagnetic
Electrical resistivity(20 °C) 26.50 nΩ·m
Thermal conductivity(300 K) 237 W·m−1·K−1
Thermal expansion(25 °C) 23.1 µm·m−1·K−1
Speed of sound (thin rod)(r.t.) (rolled) 5000 m·s−1
Young's modulus70 GPa
Shear modulus26 GPa
Bulk modulus76 GPa
Poisson ratio0.35
Mohs hardness2.75
Vickers hardness167 MPa
Brinell hardness245 MPa