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51 Sb 121.760(1)

Antimony

Metalloid
Symbol Sb
Atomic Number 51
Atomic Weight 121.760(1)
CAS Registry ID 7440-36-0
Group Name Pnictogen
Period Number 5
Block p-block
State at STP Solid

Description

Sample of Antimony ⌕ Enlarge Image

Antimony is a metalloid with a shiny silver grey color in its natural solid state. It is a crystalline solid, and as a metalloid it has poor heat and electrical conductivity traits. Antimony has an atomic mass of 121.760, a melting point of 1167.13 °F, and a boiling point of 2889 °F. The main use of antimony is as a hardener added to lead for storage batteries; antimony is also used in matches, plumbing, soldering, and as a semiconductor for diode production.

Isolation

Antimony does occur freely in nature, but not in large enough amounts to satisfy commercial needs. Isolation procedures are used to extract antimony from mineral ore.

Antimony ⌕ Enlarge Image

Antimony occurs in over 100 types of minerals. The mineral stibnite, or antimonite, is the mineral that is used most often for antimony isolation; it is a sulfide mineral composed of antimony and hydrogen sulfide. Antimony can be separated from antimonite through two processes. In the first process, antimonite is reacted with pure iron on a one to three basis; the result of the reaction forms pure antimony and iron sulfide. The second separation process of antimony uses charcoal to extract antimony from the hydrogen sulfide. In this reaction, antimonite and charcoal combined with sodium sulfate are heated resulting in a reduction reaction; the sodium sulfate is necessary to completely mix the antimonite with the charcoal. Pure antimony and carbon monoxide are produced from this reaction. Pure antimony and its compounds are toxic; the toxicity of antimony is so severe that it can even mimic arsenic and so it must be handled with caution.

General

NameAntimony
SymbolSb
Number51
Chemical seriesMetalloid
Group15
Period5
Blockp
Appearancesilvery lustrous gray
Standard atomic weight121.760(1) g·mol⁻¹
Electron configuration[Kr] 4d10 5s2 5p3
Electrons per shell2, 8, 18, 18, 5

Atomic Properties

Crystal structurerhombohedral
Oxidation states−3, 3, 5
Electronegativity2.05 (scale Pauling)
Ionization energies1st:  834  kJ·mol−1
2nd:  1594.9  kJ·mol−1
3rd:  2440  kJ·mol−1
Atomic radius145 pm
Atomic radius (calc.)133 pm
Covalent radius138 pm
Van der Waals radius

Physical Properties

Phasesolid
Density (near r.t.)6.697  g·cm−3
Liquid density at m.p.6.53  g·cm−3
Melting point903.78 K (630.63 °C, 1167.13 °F)
Boiling point1860 K (1587 °C, 2889 °F)
Critical point
Heat of fusion19.79  kJ·mol−1
Heat of vaporization193.43  kJ·mol−1
Heat capacity(25 °C) 25.23  J·mol−1·K−1

Miscellaneous

Magnetic ordering
Electrical resistivity(20 °C) 417 n Ω·m
Thermal conductivity(300 K) 24.4  W·m−1·K−1
Thermal expansion(25 °C) 11.0  µm·m−1·K−1
Speed of sound (thin rod)(20 °C) 3420 m/s
Young's modulus55  GPa
Shear modulus20 GPa
Bulk modulus42 GPa
Poisson ratio
Mohs hardness3.0
Vickers hardness
Brinell hardness294 MPa