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18 Ar 39.948(1)

Argon

Noble gas
Symbol Ar
Atomic Number 18
Atomic Weight 39.948(1)
CAS Registry ID 7440-37-1
Group Name Noble gas
Period Number 3
Block p-block
State at STP Solid

Description

Sample of Argon ⌕ Enlarge Image

Argon is a colorless, odorless, noble gas. Argon is a very stable noble gas, is one of the most common noble gases to be found on Earth, and it is nontoxic. Argon has an atomic weight of 39.948, a melting point of - 308.7 °F, and a boiling point of - 302.4 °F. Some common uses of argon include: as a component in fluorescent tubes, photo tubes, glow tubes, and electric light bulbs, to create a protective blanket in the production of reactive elements and for the growth of silicon and germanium crystals.

Isolation

Argon is isolated from the air through cryogenic fractional distillation. This process is not carried out on a small scale in laboratories, but rather through large scale processes for industrial purposes.

Argon ⌕ Enlarge Image

The atmosphere around earth is composed of 0.94% argon. Today, cryogenic fractional distillation isolates elemental argon from the air using extremely high temperatures to liquefy the air, and then extremely low temperatures to separate the argon from the liquefied elements. In this process, krypton, neon, nitrogen, oxygen, and xenon are produced.

Before technology was available to use cryogenic fractional distillation, elemental argon was isolated using a multi step system. The first step used an air separation distillation system and a low pressure column to isolate air with high concentrations of argon. The crude argon was heated and reacted with nitrogen and oxygen to form argon in water. The water was removed from the argon through condensation and absorption processes. The gas that remained was cooled to low temperatures in order to remove the small amounts of remaining nitrogen and hydrogen from the argon gas mixture. The end result was pure argon.

General

NameArgon
SymbolAr
Number18
Chemical seriesNoble gas
Group18
Period3
Blockp
Appearancecolorless
Standard atomic weight39.948(1) g·mol⁻¹
Electron configuration[Ne] 3s2 3p6
Electrons per shell2, 8, 8

Atomic Properties

Crystal structurecubic face centered
Oxidation states0
Electronegativity(Pauling scale)
Ionization energies1st: 1520.6 kJ·mol−1
2nd: 2665.8 kJ·mol−1
3rd: 3931 kJ·mol−1
Atomic radius71 pm
Atomic radius (calc.)71 pm
Covalent radius97 pm
Van der Waals radius188 pm

Physical Properties

Phasegas (At room temperature)
Density (near r.t.)(0 °C, 101.325 kPa) 1.784 g/L
Liquid density at m.p.
Melting point83.80 K (−189.35 °C, −308.83 °F)
Boiling point87.30 K (−185.85 °C, −302.53 °F)
Critical point150.87 K, 4.898 MPa
Heat of fusion1.18 kJ·mol−1
Heat of vaporization6.43 kJ·mol−1
Heat capacity(25 °C) 20.786 J·mol−1·K−1

Miscellaneous

Magnetic orderingnonmagnetic
Electrical resistivity
Thermal conductivity(300 K) 17.72 m W·m−1·K−1
Thermal expansion
Speed of sound (thin rod)(gas, 27 °C) 323 m/s
Young's modulus
Shear modulus
Bulk modulus
Poisson ratio
Mohs hardness
Vickers hardness
Brinell hardness