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85 At (210)

Astatine

Halogen
Symbol At
Atomic Number 85
Atomic Weight (210)
CAS Registry ID 7440-68-8
Group Name Halogen
Period Number 6
Block p-block
State at STP Solid

Description

Sample of Astatine ⌕ Enlarge Image

Astatine is a radioactive halogen that occurs from the decay of uranium-235 and uranium-238. It is the heaviest of all the halogens and has been named the rarest element on Earth. Astatine has an atomic weight of 210, a melting point of 576 °F, and the boiling point of this element is not currently known. Compounds of astatine have been created and studied for possible applications in nuclear medicine, but currently there are no commercial uses for astatine as it is so rare and toxic.

Isolation

The quick half life of astatine makes isolation procedures from nature impossible. As this element is not obtainable from natural sources it must be created instead.

Astatine ⌕ Enlarge Image

Astatine only has a half life of approximately 8.3 hours. Any studies or projected work that is to be done on astatine that is synthesized must be performed quickly before it disintegrates. The only way that astatine can be created is in a nuclear reactor using the element bismuth. In this process, the bismuth isotope, number 209, is bombarded with alpha particles from the nuclei of the isotope, number 4, of helium. This results in the formation of the astatine isotope number 211. The bismuth target must be cooled during this process because astatine is extremely volatile. Once this process is completed, the bismuth target is then heated to between 300 - 1112 °F. The heating process takes place under nitrogen and this reaction produces a stream of astatine in its elemental form. The minute quantities of astatine that are produced are then collected on a finger of cold glass.

General

NameAstatine
SymbolAt
Number85
Chemical seriesHalogen
Group17
Period6
Blockp
Appearancemetallic
Standard atomic weight(210) g·mol⁻¹
Electron configuration[Xe] 4f14 5d10 6s2 6p5
Electrons per shell2, 8, 18, 32, 18, 7

Atomic Properties

Crystal structure
Oxidation states±1, 3, 5, 7
Electronegativity2.2 (scale Pauling)
Ionization energies1st: 890±40 kJ/mol
Atomic radius
Atomic radius (calc.)
Covalent radius
Van der Waals radius

Physical Properties

Phasesolid
Density (near r.t.)
Liquid density at m.p.
Melting point575 K (302 °C, 576 °F)
Boiling point610 K (337 °C, ? 639 °F)
Critical point
Heat of fusion
Heat of vaporizationca. 40  kJ·mol−1
Heat capacity

Miscellaneous

Magnetic ordering
Electrical resistivity
Thermal conductivity(300 K) 1.7  W·m−1·K−1
Thermal expansion
Speed of sound (thin rod)
Young's modulus
Shear modulus
Bulk modulus
Poisson ratio
Mohs hardness
Vickers hardness
Brinell hardness