sciencefairadventure
35 Br 79.904(1)

Bromine

Halogen
Symbol Br
Atomic Number 35
Atomic Weight 79.904(1)
CAS Registry ID 7726-95-6
Group Name Halogen
Period Number 4
Block p-block
State at STP Solid

Description

Sample of Bromine ⌕ Enlarge Image

Bromine is a halogen that is a reddish brown color in its natural liquid state. It is a highly reactive element and it is the only nonmetal that is a liquid at room temperature. Bromine has an atomic mass of 79.904, a melting point of 19 °F, and a boiling point of 137.8 °F. Some common uses of bromine include: as a fumigant and flame retardant, as a component in water purification, as a component in dyes, disinfectants, and medicines.

Isolation

Bromine does not occur free in nature but is found in the form of bromide salts and crustal rock. Isolation processes to extract bromine from these sources are used for commercial bromine purposes.

Bromine ⌕ Enlarge Image

Bromine salt is present in sea water and is recovered from water in brine wells and out of the Dead Sea. The salt of bromine, bromide, is collected out of seawater by treating the seawater with a chlorine gas and then flushing the seawater and chlorine gas with air; the result of the reaction causes bromide to be oxidized to bromine. This process is used for large scale bromine isolation purposes.

Bromine can be isolated on a small scale laboratory setting by reacting solid sodium bromide salt with sulphuric acid. From this reaction, bromine gas is formed; additional amounts of sulphuric acid will oxidize the bromine gas to form pure bromine and sulfur dioxide. This reaction will only work with sodium bromide salt; it will not work if using the bromide salt containing chlorides or fluorides.

Pure bromine is toxic when inhaled and is corrosive to human tissue; this element must be handled carefully in its isolated form.

General

NameBromine
SymbolBr
Number35
Chemical seriesHalogen
Group17
Period4
Blockp
Appearancegas/liquid: red-brown
Standard atomic weight79.904(1) g·mol⁻¹
Electron configuration[Ar] 4s2 3d10 4p5
Electrons per shell2, 8, 18, 7

Atomic Properties

Crystal structureorthorhombic
Oxidation states±1, 5 (strongly acidic oxide)
Electronegativity2.96 (scale Pauling)
Ionization energies1st:  1139.9  kJ·mol−1
2nd:  2103  kJ·mol−1
3rd:  3470  kJ·mol−1
Atomic radius115 pm
Atomic radius (calc.)94 pm
Covalent radius114 pm
Van der Waals radius185 pm

Physical Properties

Phaseliquid
Density (near r.t.)(Br2, liquid) 3.1028  g·cm−3
Liquid density at m.p.
Melting point265.8 K (-7.3 °C, 19 °F)
Boiling point332.0 K (58.8 °C, 137.8 °F)
Critical point588 K, 10.34 MPa
Heat of fusion(Br2) 10.571  kJ·mol−1
Heat of vaporization(Br2) 29.96  kJ·mol−1
Heat capacity(25 °C) (Br2) 75.69  J·mol−1·K−1

Miscellaneous

Magnetic orderingnonmagnetic
Electrical resistivity(20 °C) 7.8×1010  Ω·m
Thermal conductivity(300 K) 0.122  W·m−1·K−1
Thermal expansion
Speed of sound (thin rod)(20 °C) ? 206 m/s
Young's modulus
Shear modulus
Bulk modulus
Poisson ratio
Mohs hardness
Vickers hardness
Brinell hardness