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55 Cs 132.9054519(2)

Caesium

Alkali metal
Symbol Cs
Atomic Number 55
Atomic Weight 132.9054519(2)
CAS Registry ID 7440-46-2
Group Name Alkali metal
Period Number 6
Block s-block
State at STP Solid

Description

Sample of Caesium ⌕ Enlarge Image

Cesium is an alkali metal that has a bright gold color in its natural solid state. While cesium is considered to be a solid, it has a low melting point and is a liquid near room temperatures. Cesium is the least abundant non-radioactive alkali metal, and is the second most electropositive alkali metal. Cesium has an atomic weight of 132.9054519, a melting point of 83.19 °F, and a boiling point of 1240 °F. Cesium is most commonly used as a drilling fluid for oil.

Isolation

Cesium is found in nature with other compounds in mineral ore. Multiple isolation procedures are used to extract cesium from its ore.

Caesium ⌕ Enlarge Image

Cesium occurs in such minerals as lepidolite and pollucite. Lepidolite is a phyllosilicate mineral that contains cesium in addition to many other minerals, and phyllosilicate is a xeolite mineral. Most of the cesium that is extracted for commercial uses comes from phyllosilicate. Electrolysis of cesium cyanide, and thermal decomposition of its azide form are some of the ways in which cesium can be isolated. The extraction process of cesium includes melting the ore it occurs in and extracting the liquid cesium chloride; electrolysis using cesium as the positive cathode and chlorine as the anode can further isolate the cesium. Cesium can also be extracted from cesium chloride by heating the compound to a molten liquid and adding metallic sodium to the mixture. During this reaction, the cesium becomes highly volatile and pure cesium and sodium chloride are produced. Further distillation processes can remove any contaminants that might be present in small amounts.

General

NameCaesium
SymbolCs
Number55
Chemical seriesAlkali metal
Group1
Period6
Blocks
Appearancesilvery gold
Standard atomic weight132.9054519(2) g·mol⁻¹
Electron configuration[Xe] 6s1
Electrons per shell2, 8, 18, 18, 8, 1

Atomic Properties

Crystal structurebody centered cubic
Oxidation states1 (strongly basic oxide)
Electronegativity0.79 (scale Pauling)
Ionization energies1st: 375.7 kJ/mol
2nd: 2234.3 kJ/mol
3rd: 3400 kJ/mol
Atomic radius260  pm
Atomic radius (calc.)298 pm
Covalent radius225 pm
Van der Waals radius

Physical Properties

Phasesolid
Density (near r.t.)1.93  g·cm−3
Liquid density at m.p.1.843  g·cm−3
Melting point301.59 K (28.44 °C, 83.19 °F)
Boiling point944 K (671 °C, 1240 °F)
Critical point1938 K, 9.4 MPa
Heat of fusion2.09  kJ·mol−1
Heat of vaporization63.9  kJ·mol−1
Heat capacity(25 °C) 32.210  J·mol−1·K−1

Miscellaneous

Magnetic ordering
Electrical resistivity(20 °C) 205 n Ω·m
Thermal conductivity(300 K) 35.9  W·m−1·K−1
Thermal expansion(25 °C) 97  µm·m−1·K−1
Speed of sound (thin rod)
Young's modulus1.7  GPa
Shear modulus
Bulk modulus1.6  GPa
Poisson ratio
Mohs hardness0.2
Vickers hardness
Brinell hardness0.14 MPa