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20 Ca 40.078(4)

Calcium

Alkaline earth metal
Symbol Ca
Atomic Number 20
Atomic Weight 40.078(4)
CAS Registry ID 7440-70-2
Group Name Alkaline earth metal
Period Number 4
Block s-block
State at STP Solid

Description

Sample of Calcium ⌕ Enlarge Image

Calcium is an alkaline earth metal that is a silvery white solid in its natural state. Calcium readily reacts with water and it forms a layer of oxide and nitride coating if it is exposed to the air. Calcium has an atomic weight of 40.078, a melting point of 1548 °F, and a boiling point of 2703 °F. Some common uses of calcium include: in the formation of quicklime, limestone, and slaked lime, as an ingredient in Portland cement, in calcium chloride for ice removal on roads, as an ingredient in vitamins and food additives, and as an ingredient in fertilizers.

Isolation

Calcium is not found in its pure form in nature, and there are two main processes that are used to isolate calcium.

Calcium ⌕ Enlarge Image

Calcium in the form of sedentary rock can be found in such minerals as calcite, dolomite, and gypsum. The most frequently used calcium isolation method for industrial purposes uses electrolysis. During this process, calcium chloride is produced by reacting hydrochloric acid with calcium carbonate. The results of this reaction include calcium chloride, water, and carbon dioxide. The liquid calcium chloride is then subject to electrolysis; the cathode calcium is separated from the anode chloride.

There are two processes that can be used to isolate a small amount of calcium. The first process uses the reducing reaction between lime, (CaO), and aluminum; the results of this reaction include pure calcium and Ca3Al2O6. The second isolation process uses the reducing reaction between calcium chloride with metal sodium; the end result of this reaction is pure calcium and sodium chloride. These processes are not frequently used as pure calcium that has been isolated for industrial purposes is easily obtained commercially.

General

NameCalcium
SymbolCa
Number20
Chemical seriesAlkaline earth metal
Group2
Period4
Blocks
Appearancesilvery white
Standard atomic weight40.078(4) g·mol⁻¹
Electron configuration[Ar] 4s2
Electrons per shell2, 8, 8, 2

Atomic Properties

Crystal structurecubic face centered
Oxidation states2 (strongly basic oxide)
Electronegativity1.00 (Pauling scale)
Ionization energies1st: 589.8 kJ·mol−1
2nd: 1145.4 kJ·mol−1
3rd: 4912.4 kJ·mol−1
Atomic radius180 pm
Atomic radius (calc.)194 pm
Covalent radius174 pm
Van der Waals radius

Physical Properties

Phasesolid
Density (near r.t.)1.55 g·cm−3
Liquid density at m.p.1.378 g·cm−3
Melting point1115 K (842 °C, 1548 °F)
Boiling point1757 K (1484 °C, 2703 °F)
Critical point
Heat of fusion8.54 kJ·mol−1
Heat of vaporization154.7 kJ·mol
Heat capacity(25 °C) 25.929 J·mol−1·K−1

Miscellaneous

Magnetic orderingparamagnetic
Electrical resistivity(20 °C) 33.6 nΩ·m
Thermal conductivity(300 K) 201 W·m−1·K−1
Thermal expansion(25 °C) 22.3 µm·m−1·K−1
Speed of sound (thin rod)(20 °C) 3810 m/s
Young's modulus20 GPa
Shear modulus7.4 GPa
Bulk modulus17 GPa
Poisson ratio0.31
Mohs hardness1.75
Vickers hardness
Brinell hardness167 MPa