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27 Co 58.933195(5)

Cobalt

Transition metal
Symbol Co
Atomic Number 27
Atomic Weight 58.933195(5)
CAS Registry ID 7440-48-4
Group Name (none)
Period Number 4
Block d-block
State at STP Solid

Description

Sample of Cobalt ⌕ Enlarge Image

Cobalt is one of the transition metals with ferromagnetic properties; it is a metal with a metallic gray color in its natural solid state. Cobalt has an atomic weight of 58.933195, a melting point of 2723 °F, and a boiling point of 5301 °F. Some common uses of cobalt include: as a component in metallic alloys for high speed steels, as a component in super-alloys for turbine aircraft engine parts, as a component in magnetic recording devices, and as a component in electroplating.

Isolation

Cobalt is never found freely in nature, and there are isolation procedures that are used to isolate cobalt from mineral ores.

Cobalt ⌕ Enlarge Image

Cobalt is generally isolated from byproducts in copper, nickel, and lead production. The major ores that contain cobalt is cobaltite, erythrite, glaucodot, and skutterudite. In the process which results in isolation of cobalt, the mineral ore is first heated to form a mixture of metals and their metal oxides. The addition of sulphuric acid to the mixture causes copper to come out of the mixture as a residue, and iron, cobalt, and nickel form their sulphates. The addition of sodium hypochlorite to the resulting mixture causes cobalt to precipitate out in a trihydroxide form. The trihydroxide of cobalt is then heated to form cobalt oxide and water. In the final step of isolation, the cobalt is reduced with carbon in the form of charcoal resulting in pure cobalt and carbon dioxide.

The isolation procedures of cobalt are very rarely performed in a laboratory as the process is highly inefficient and pure cobalt is available commercially.

General

NameCobalt
SymbolCo
Number27
Chemical seriesTransition metal
Group9
Period4
Blockd
Appearancemetallic with gray tinge
Standard atomic weight58.933195(5) g·mol⁻¹
Electron configuration[Ar] 3d7 4s2
Electrons per shell2, 8, 15, 2

Atomic Properties

Crystal structurehexagonal
Oxidation states2, 3 (amphoteric oxide)
Electronegativity1.88 (Pauling scale)
Ionization energies1st: 760.4 kJ·mol−1
2nd: 1648 kJ·mol−1
3rd: 3232 kJ·mol−1
Atomic radius135 pm
Atomic radius (calc.)152 pm
Covalent radius126 pm
Van der Waals radius

Physical Properties

Phase
Density (near r.t.)8.90 g·cm−3
Liquid density at m.p.7.75 g·cm−3
Melting point1768 K (1495 °C, 2723 °F)
Boiling point3200 K (2927 °C, 5301 °F)
Critical point
Heat of fusion16.06 kJ·mol−1
Heat of vaporization377 kJ·mol−1
Heat capacity(25 °C) 24.81 J·mol−1·K−1

Miscellaneous

Magnetic orderingferromagnetic
Electrical resistivity(20 °C) 62.4 nΩ·m
Thermal conductivity(300 K) 100 W·m−1·K−1
Thermal expansion(25 °C) 13.0 µm·m−1·K−1
Speed of sound (thin rod)(20 °C) 4720 m/s
Young's modulus209 GPa
Shear modulus75 GPa
Bulk modulus180 GPa
Poisson ratio0.31
Mohs hardness5.0
Vickers hardness1043 MPa
Brinell hardness700 MPa