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68 Er 167.259(3)

Erbium

Lanthanide
Symbol Er
Atomic Number 68
Atomic Weight 167.259(3)
CAS Registry ID 7440-52-0
Group Name Lanthanoid
Period Number 6
Block f-block
State at STP Solid

Description

Sample of Erbium ⌕ Enlarge Image

Erbium is a lanthanide that has a silvery white appearance in its natural solid state. It is soft and stable in the air, and has lower oxidation characteristics as compared to other rare earth metals. Erbium has an atomic weight of 167.259, a melting point of 2784 °F, and a boiling point of 5194 °F. Some common uses of erbium include: as a neutron absorber, as a component in some alloys to improve workability, as a coloring in glass and porcelain, as the pink color in cubic zirconium and other cheaper forms of jewelry, and as a component in optical communications.

Isolation

Erbium does not occur in its free state in nature, but it does occur frequently in mineral and sand ores with other rare earth elements.

Erbium ⌕ Enlarge Image

The isolation procedures that are used to extract erbium from the ores it occurs in are highly complex. The complexity of these procedures are due to the fact that erbium only occurs along with other rare elements or lanthanides; these elements all have similar characteristics and so they are not easily separated. The many different chemical reactions that must be performed to isolate pure erbium do not allow for erbium isolation on a small scale laboratory basis.

Erbium can be isolated from monazite sand ores using ion exchange procedures. Erbium is also extracted from xenotime and euxenite minerals. Ion adsorption procedures are also used to separate erbium out of specific types of clays that it occurs in. The extraction of erbium from mineral sources begins with treating the minerals with sulfuric acid, hydrochloric acid, and sodium hydroxide. Further processes using solvent extraction, ion exchange chromatography, and heated reactions with calcium are used to yield pure erbium.

General

NameErbium
SymbolEr
Number68
Chemical seriesLanthanide
Groupn/a
Period6
Blockf
Appearancesilvery white
Standard atomic weight167.259(3) g·mol⁻¹
Electron configuration[Xe] 4f12 6s2
Electrons per shell2, 8, 18, 30, 8, 2

Atomic Properties

Crystal structurehexagonal
Oxidation states3 (basic oxide)
Electronegativity1.24 (scale Pauling)
Ionization energies1st:  589.3  kJ·mol−1
2nd:  1150  kJ·mol−1
3rd:  2194  kJ·mol−1
Atomic radius175  pm
Atomic radius (calc.)226  pm
Covalent radius
Van der Waals radius

Physical Properties

Phasesolid
Density (near r.t.)9.066  g·cm−3
Liquid density at m.p.8.86  g·cm−3
Melting point1802 K (1529 °C, 2784 °F)
Boiling point3141 K (2868 °C, 5194 °F)
Critical point
Heat of fusion19.90  kJ·mol−1
Heat of vaporization280  kJ·mol−1
Heat capacity(25 °C) 28.12  J·mol−1·K−1

Miscellaneous

Magnetic ordering
Electrical resistivity(r.t.) (poly) 0.860 µΩ·m
Thermal conductivity(300 K) 14.5  W·m−1·K−1
Thermal expansion(r.t.) (poly) 12.2 µm/(m·K)
Speed of sound (thin rod)(20 °C) 2830 m/s
Young's modulus69.9  GPa
Shear modulus28.3  GPa
Bulk modulus44.4  GPa
Poisson ratio0.237
Mohs hardness
Vickers hardness589  MPa
Brinell hardness814  MPa