sciencefairadventure
63 Eu 151.964(1)

Europium

Lanthanide
Symbol Eu
Atomic Number 63
Atomic Weight 151.964(1)
CAS Registry ID 7440-53-1
Group Name Lanthanoid
Period Number 6
Block f-block
State at STP Solid

Description

Sample of Europium ⌕ Enlarge Image

Europium is a lanthanide that has a shiny, silvery, white color in its natural solid state. It oxidizing in air, and will ignite in air and high temperatures. Europium has an atomic weight of 151.964, a melting point of 1519 °F, and a boiling point of 2784 °F. Some common uses of europium include: as a doper component to produce some types of glass and lasers, in the diagnosis of genetic diseases, as the re phosphor in T.V. and fluorescent lamps, and in trace element studies.

Isolation

Europium is never found in its free state in nature, but it occurs in minerals with contain other rare elements and lanthanides. Extraction processes can be used to isolate europium from these elements.

Europium ⌕ Enlarge Image

Europium is found in nature in the minerals bastnasite and monazite. Due to the fact that these minerals are also composed of other rare earth elements and lanthanides, the isolation process of europium is a highly complicated multi-step process. Due to the complexity of the europium isolation process, it is never performed on a small scale laboratory basis.

The extraction and isolation process of europium begins with treating the minerals it occurs in with sulfuric acid, hydrochloric acid, and sodium hydroxide. This process isolates the elements in the minerals out in their salt forms. Europium is further isolated by repeated solvent extractions and ion exchange chromatography. These processes extract europium out of solution in a chloride form. Electrolysis with sodium chloride in a graphite cell is needed to further purify the europium. The result from electrolysis yields pure europium and chlorine gas. It is not known currently whether pure europium presents any toxic hazards.

General

NameEuropium
SymbolEu
Number63
Chemical seriesLanthanide
Groupn/a
Period6
Blockf
Appearancesilvery white
Standard atomic weight151.964(1) g·mol⁻¹
Electron configuration[Xe] 4f7 6s2
Electrons per shell2, 8, 18, 25, 8, 2

Atomic Properties

Crystal structuresimple cubic (body centered)
Oxidation states3, 2 (mildly basic oxide)
Electronegativity? 1.2 (scale Pauling)
Ionization energies1st:  547.1  kJ·mol-1
2nd:  1085  kJ·mol-1
3rd:  2404  kJ·mol-1
Atomic radius185  pm
Atomic radius (calc.)231  pm
Covalent radius
Van der Waals radius

Physical Properties

Phasesolid
Density (near r.t.)5.264  g·cm-3
Liquid density at m.p.5.13  g·cm-3
Melting point1099 K (826 °C, 1519 °F)
Boiling point1802 K (1529 °C, 2784 °F)
Critical point
Heat of fusion9.21  kJ·mol-1
Heat of vaporization176  kJ·mol-1
Heat capacity(25 °C) 27.66  J·mol-1·K-1

Miscellaneous

Magnetic ordering
Electrical resistivity(r.t.) (poly) 0.900 µΩ·m
Thermal conductivity(300 K) est. 13.9  W·m−1·K−1
Thermal expansion(r.t.) (poly) 35.0 µm/(m·K)
Speed of sound (thin rod)
Young's modulus18.2  GPa
Shear modulus7.9  GPa
Bulk modulus8.3  GPa
Poisson ratio0.152
Mohs hardness
Vickers hardness167  MPa
Brinell hardness