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9 F 18.9984032(5)

Fluorine

Halogen
Symbol F
Atomic Number 9
Atomic Weight 18.9984032(5)
CAS Registry ID 7782-41-4
Group Name Halogen
Period Number 2
Block p-block
State at STP Solid

Description

Sample of Fluorine ⌕ Enlarge Image

The element fluorine is a halogen, and in its normal state fluorine is a yellow-brown gas with a foul odor. Fluorine has an atomic weight of 18.9984032, a melting point of -363.32 °F, and a boiling point of -306.62 °F. Fluorine, as the most reactive of the elements, will react with almost all inorganic and organic matter. Some current uses of fluorine include: as a hydrocarbon for use in refrigerators and air conditioners, as a tooth decay preventative in very small amounts in water and toothpaste, and in the production of high temperature plastics.

Isolation

The high reactivity of fluorine has limited the type of procedures that are available to use in fluorine isolation. Fluorine is hardly ever isolated in a laboratory because of safety reasons.

Fluorine ⌕ Enlarge Image

A process named Moissan’s process is used to isolate fluorine for industrial purposes. During this process, a solution of potassium hydrogen fluoride is electrolyzed in liquid hydrogen fluoride. The liquid hydrogen fluoride is a necessary component of the reaction because it does not conduct electricity. During the electrolysis process, the fluoride is isolated from other elements by passing an electric current through the compounds. Moissan’s process uses electrodes made from platinum and iridium that are placed in a platinum holder and cooled to -122 °F. As the electric current passes through, the negative electrode isolate outs the hydrogen as the positive electrode isolates the fluorine. One another method can separate fluorine through a heated chemical reaction between K2MnF6 and 2SbF5 instead of using electrolysis; this isolation process is not used though because it is inefficient. Pure fluorine and fluoride ions are extremely dangerous as this element is very reactive and toxic.

General

NameFluorine
SymbolF
Number9
Chemical seriesHalogen
Group17
Period2
Blockp
AppearanceYellowish brown gas
Standard atomic weight18.9984032(5) g·mol⁻¹
Electron configuration1s2 2s2 2p5
Electrons per shell2, 7

Atomic Properties

Crystal structurecubic
Oxidation states−1 (strongly acidic oxide)
Electronegativity3.98 (Pauling scale)
Ionization energies1st: 1681.0 kJ·mol−1
2nd: 3374.2 kJ·mol−1
3rd: 6050.4 kJ·mol−1
Atomic radius50 pm
Atomic radius (calc.)42 pm
Covalent radius71 pm
Van der Waals radius147 pm

Physical Properties

Phasegas
Density (near r.t.)(0 °C, 101.325 kPa) 1.7 g/L
Liquid density at m.p.
Melting point53.53 K (-219.62 °C, -363.32 °F)
Boiling point85.03 K (-188.12 °C, -306.62 °F)
Critical point144.13 K, 5.172 MPa
Heat of fusion(F2) 0.510 kJ·mol−1
Heat of vaporization(F2) 6.62 kJ·mol−1
Heat capacity(25 °C) (F2) 31.304 J·mol−1·K−1

Miscellaneous

Magnetic orderingnonmagnetic
Electrical resistivity
Thermal conductivity(300 K) 27.7 m W·m−1·K−1
Thermal expansion
Speed of sound (thin rod)
Young's modulus
Shear modulus
Bulk modulus
Poisson ratio
Mohs hardness
Vickers hardness
Brinell hardness