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87 Fr (223)

Francium

Alkali metal
Symbol Fr
Atomic Number 87
Atomic Weight (223)
CAS Registry ID 7440-73-5
Group Name Alkali metal
Period Number 7
Block s-block
State at STP Solid

Description

Sample of Francium ⌕ Enlarge Image

Francium is a highly radioactive element that has the lowest electronegativity of all the elements. This element is so radioactive that not much is really known about it. It is classified as an alkali metal, but no one knows whether it is a solid or liquid. The melting point is estimated at 80 ° F, and the boiling point is not yet known or even approximated. Francium has an atomic weight of 223 and is one of the rarest elements on Earth second only to astatine.

Isolation

Francium is a naturally occurring element that quickly decays into astatine, radium, and radon. Its decay rate is so quick that it has not yet been isolated.

Francium ⌕ Enlarge Image

Trace amounts of francium have been found in uranium and thorium mineral ores. In these ores, the francium element is present in an isotope form, number 223. Isolation has so far proved unsuccessful as any element that is formed immediately decays again; it has a half life of only 22 minutes. Francium has been successfully synthesized, but this too is an extremely complicated procedure and only very minute amounts can be synthesized. A nuclear reaction involving an isotope of gold and oxygen will produce francium isotopes; the isotopes are then isolated using a magneto-optic trap. Radium bombardment with neutrons and thorium protons can also synthesize francium. Francium that has been created has been held as an ultra-cold gas; in this state the atoms of the element were close to absolute zero. The very tiny amounts of francium that have been synthesized have been so small that no measurements of the weight could be obtained.

General

NameFrancium
SymbolFr
Number87
Chemical seriesAlkali metal
Group1
Period7
Blocks
Appearancemetallic
Standard atomic weight(223) g·mol⁻¹
Electron configuration[Rn] 7s1
Electrons per shell2, 8, 18, 32, 18, 8, 1

Atomic Properties

Crystal structurecubic body centered
Oxidation states1 (strongly basic oxide)
Electronegativity0.7 (scale Pauling)
Ionization energies1st: 380 kJ/mol
Atomic radius
Atomic radius (calc.)
Covalent radius
Van der Waals radius

Physical Properties

Phasesolid
Density (near r.t.)1.87  g·cm−3
Liquid density at m.p.
Melting point300 K (27 °C, 80 °F)
Boiling point950 K (677 °C, ? 1250 °F)
Critical point
Heat of fusionca. 2  kJ·mol−1
Heat of vaporizationca. 65  kJ·mol−1
Heat capacity

Miscellaneous

Magnetic ordering
Electrical resistivity3 µΩ·m
Thermal conductivity(300 K) ? 15  W·m−1·K−1
Thermal expansion
Speed of sound (thin rod)
Young's modulus
Shear modulus
Bulk modulus
Poisson ratio
Mohs hardness
Vickers hardness
Brinell hardness