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49 In 114.818(3)

Indium

Poor metal
Symbol In
Atomic Number 49
Atomic Weight 114.818(3)
CAS Registry ID 7440-74-6
Group Name (none)
Period Number 5
Block p-block
State at STP Solid

Description

Sample of Indium ⌕ Enlarge Image

Indium is one of the poor metals that has a bright, lustrous, silver grey color in its natural solid state. It is a soft and malleable metal, and it is minutely radioactive. Indium has an atomic weight of 114.818, a melting point of 313.88 °F, and a boiling point of 3762 °F. Some common uses of indium include: in the form of indium tin oxide thin films to create LCDs, as a component of some low melting alloys, as a component in light-emitting LEDs, and as a component in some mirrors and glass.

Isolation

Indium occurs most often in nature with zinc ores. Isolation procedures used to extract indium from zinc is performed on a commercial scale.

Indium ⌕ Enlarge Image

Indium is found in ores which contain copper, iron, lead, and zinc. Most of the indium that is isolated commercially is extracted from zinc ores, and sometimes lead ores. It can be isolated from the zinc using electrolysis processes between indium salts and water. Indium is also a by-product of lead and zinc formation. During the electrolysis process, the salts of indium that were initially formed from beginning isolation processes are dissolved in water. A positive electrode, the anode, and the negative electrode, the cathode, are used to run an electric current through the solution. Indium is collected out of the solution. High purity indium that is used for electronic purposes must undergo further extraction techniques once it has been isolated from the solution in order to remove any contaminants. While pure indium is not considered to be hazardous, some indium compounds can be toxic so it should be handled with caution.

General

NameIndium
SymbolIn
Number49
Chemical seriesPoor metal
Group13
Period5
Blockp
Appearancesilvery lustrous gray
Standard atomic weight114.818(3) g·mol⁻¹
Electron configuration[Kr] 4d10 5s2 5p1
Electrons per shell2, 8, 18, 18, 3

Atomic Properties

Crystal structuretetragonal
Oxidation states3 (amphoteric oxide)
Electronegativity1.78 (scale Pauling)
Ionization energies1st:  558.3  kJ·mol−1
2nd:  1820.7  kJ·mol−1
3rd:  2704  kJ·mol−1
Atomic radius155 pm
Atomic radius (calc.)156 pm
Covalent radius144 pm
Van der Waals radius193 pm

Physical Properties

Phasesolid
Density (near r.t.)7.31  g·cm−3
Liquid density at m.p.7.02  g·cm−3
Melting point429.75 K (156.60 °C, 313.88 °F)
Boiling point2345 K (2072 °C, 3762 °F)
Critical point
Heat of fusion3.281  kJ·mol−1
Heat of vaporization231.8  kJ·mol−1
Heat capacity(25 °C) 26.74  J·mol−1·K−1

Miscellaneous

Magnetic ordering
Electrical resistivity(20 °C) 83.7 n Ω·m
Thermal conductivity(300 K) 81.8  W·m−1·K−1
Thermal expansion(25 °C) 32.1  µm·m−1·K−1
Speed of sound (thin rod)(20 °C) 1215 m/s
Young's modulus11 GPa
Shear modulus
Bulk modulus
Poisson ratio
Mohs hardness1.2
Vickers hardness
Brinell hardness8.83 MPa