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25 Mn 54.938045(5)

Manganese

Transition metal
Symbol Mn
Atomic Number 25
Atomic Weight 54.938045(5)
CAS Registry ID 7439-96-5
Group Name (none)
Period Number 4
Block d-block
State at STP Solid

Description

Sample of Manganese ⌕ Enlarge Image

Manganese is a transition metal that has a silvery grey white metallic color in its natural solid state. It is a hard, brittle, element that is easily oxidized. Manganese has an atomic weight of 54.938045, a melting point of 2275 °F, and a boiling point of 3742 °F. Some common uses of manganese include: as a component in metallic alloys, as a dioxide used to produced oxygen and chlorine, for use in iron and steel production, and as an ingredient in some types of stainless steel.

Isolation

Manganese is found freely in nature, but there are isolation processes that are used to isolate manganese for industrial purposes.

Manganese ⌕ Enlarge Image

Manganese that is isolated comes from minerals such as pyrolusite, (MnO2), and rhodochrosite, (MnCO3). Pyrolusite is a mineral which is composed mainly of manganese dioxide, and rhodochrosite is a mineral composed of manganese carbonate.

Magnesium was first isolated by using electrolysis on manganese chloride; the electrolysis process was carried out by placing the manganese chloride in a porous cell which was surrounded by hydrochloric acid in a carbon crucible.

Other reduction methods reduce manganese fluoride through using the metal sodium. The thermite process has been used to isolate manganese from pyrolusite by heating the mineral in proportion with 30% sulphuric acid; manganous oxide is produced after this process through heating, cooling, and heating steps using aluminum in the final step. Lime and fluorspar is used as the flux in this process. Another isolation method isolates a very pure form of manganese by reducing manganese and mercury containing alloys, or amalgams, with hydrogen.

General

NameManganese
SymbolMn
Number25
Chemical seriesTransition metal
Group7
Period4
Blockd
Appearancesilvery metallic
Standard atomic weight54.938045(5) g·mol⁻¹
Electron configuration[Ar] 4s2 3d5
Electrons per shell2, 8, 15

Atomic Properties

Crystal structurecubic A12
Oxidation states7, 6, 4, 2, 3 (oxides: acidic, basic or amphoteric)
Electronegativity1.55 (Pauling scale)
Ionization energies1st: 717.3 kJ·mol−1
2nd: 1509.0 kJ·mol−1
3rd: 3248 kJ·mol−1
Atomic radius140 pm
Atomic radius (calc.)161 pm
Covalent radius139 pm
Van der Waals radius

Physical Properties

Phasesolid
Density (near r.t.)7.21 g·cm−3
Liquid density at m.p.5.95 g·cm−3
Melting point1519 K (1246 °C, 2275 °F)
Boiling point2334 K (2061 °C, 3742 °F)
Critical point
Heat of fusion12.91 kJ·mol−1
Heat of vaporization221 kJ·mol−1
Heat capacity(25 °C) 26.32 J·mol−1·K−1

Miscellaneous

Magnetic orderingparamagnetic
Electrical resistivity(20 °C) 1.44 µΩ·m
Thermal conductivity(300 K) 7.81 W·m−1·K−1
Thermal expansion(25 °C) 21.7 µm·m−1·K−1
Speed of sound (thin rod)(20 °C) 5150 m/s
Young's modulus198 GPa
Shear modulus
Bulk modulus120 GPa
Poisson ratio
Mohs hardness6.0
Vickers hardness
Brinell hardness196 MPa