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60 Nd 144.242(3)

Neodymium

Lanthanide
Symbol Nd
Atomic Number 60
Atomic Weight 144.242(3)
CAS Registry ID 7440-00-8
Group Name Lanthanoid
Period Number 6
Block f-block
State at STP Solid

Description

Sample of Neodymium ⌕ Enlarge Image

Neodymium is a lanthanide that has a silvery-yellow bright color in its natural solid state. It is a rare earth element, and it oxidizes easily when exposed to air. Neodymium has an atomic weight of 144.242, a melting point of 1875 °F, and a boiling point of 5565 °F. Some common uses of neodymium include: in the form of neodymium magnets which are some of the strongest permanent magnets in the world, to color glass in red and grey colors, as a colorant for enamels, and in incandescent lamps.

Isolation

Neodymium never occurs in its free form in nature, and extraction processes are needed to isolate neodymium from the compounds it occurs in.

Neodymium ⌕ Enlarge Image

Neodymium is found most often in nature in Misch metal, monazite sand, and the mineral bastnasite. Due to the fact that these minerals and compounds also contain lanthanides and other rare earth elements, it is difficult to isolate neodymium. The process of neodymium isolation and extraction is highly complex; due to the complexity of the process, neodymium is never isolated on a small scale laboratory basis.

The first isolation process of neodymium involves extracting the lanthanides and metals out of the ores in their salt form. This step is carried out using sulphuric acid, hydrochloric acid, and sodium hydroxide. To further isolation the neodymium from other lanthanides and metals, procedures such as solvent extractions and ion exchange chromatography are used. Once neodymium has been reduced to its fluoride form using these processes, it can be reacted with pure calcium metal in a heated chamber to form pure neodymium and calcium fluoride. Some calcium contaminants remain in the neodymium, and vacuum processes are used to remove any of these contaminants.

General

NameNeodymium
SymbolNd
Number60
Chemical seriesLanthanide
Groupn/a
Period6
Blockf
Appearancesilvery white
Standard atomic weight144.242(3) g·mol⁻¹
Electron configuration[Xe] 4f4 6s2
Electrons per shell2, 8, 18, 22, 8, 2

Atomic Properties

Crystal structurehexagonal
Oxidation states3 (mildly basic oxide)
Electronegativity1.14 (scale Pauling)
Ionization energies1st:  533.1  kJ·mol−1
2nd:  1040  kJ·mol−1
3rd:  2130  kJ·mol−1
Atomic radius185  pm
Atomic radius (calc.)206  pm
Covalent radius
Van der Waals radius

Physical Properties

Phasesolid
Density (near r.t.)7.01  g·cm−3
Liquid density at m.p.6.89  g·cm−3
Melting point1297 K (1024 °C, 1875 °F)
Boiling point3347 K (3074 °C, 5565 °F)
Critical point
Heat of fusion7.14  kJ·mol−1
Heat of vaporization289  kJ·mol−1
Heat capacity(25 °C) 27.45  J·mol−1·K−1

Miscellaneous

Magnetic orderingferromagnetic
Electrical resistivity(r.t.) (α, poly) 643 nΩ·m
Thermal conductivity(300 K) 16.5  W·m−1·K−1
Thermal expansion(r.t.) (α, poly) 9.6 µm/(m·K)
Speed of sound (thin rod)(20 °C) 2330 m/s
Young's modulus(α form) 41.4  GPa
Shear modulus(α form) 16.3  GPa
Bulk modulus(α form) 31.8  GPa
Poisson ratio(α form) 0.281
Mohs hardness
Vickers hardness343  MPa
Brinell hardness265  MPa