sciencefairadventure
28 Ni 58.6934(2)

Nickel

Transition metal
Symbol Ni
Atomic Number 28
Atomic Weight 58.6934(2)
CAS Registry ID 7440-02-0
Group Name (none)
Period Number 4
Block d-block
State at STP Solid

Description

Sample of Nickel ⌕ Enlarge Image

Nickel is one of the transition metals that has a lustrous gold and metallic silver color in its natural solid state. Nickel has an atomic weight of 58.6934, a melting point of 2651 °F, and a boiling point of 5275 °F. While nickel is a reactive element, it does not oxidize easily when exposed to air. Some common uses of nickel include: as a component in magnets and coins, as a component in metallic alloys, as a component of stainless steel, as a component in nickel cast iron.

Isolation

Nickel that is used for commercial purposes is isolated from two primary types or ores: the laterite ore minerals, and sulfide deposits.

Nickel ⌕ Enlarge Image

Laterite mineral ores are primarily composed of limonite, (Fe, Ni)O(OH), and garnierite, (Ni, Mg)3Si2O5(OH). The sulfide deposits are composed primarily of pentlandite, (Ni,Fe)9S8. Nickel is isolated using the principles of extractive metallurgy. During this isolation process, the nickel ore is heated and then undergoes reduction; this heating and reduction step results in a composition of nickel that is approximately ¾ pure. To isolate the nickel further for almost 100% purity, the Mond process is used.

During the Mond process, nickel is combined with carbon monoxide and heated to approximately 122 °F. The result of the reaction causes a volatile nickel carbonyl to form, and other impurities are left in a solid state. The nickel carbonyl is then brought into a chamber where it is exposed to high temperatures along with nickel spheres which are constantly moving; over time, the nickel carbonyl disintegrates and pure nickel is deposited into the nickel spheres forming solid nickel pellets.

General

NameNickel
SymbolNi
Number28
Chemical seriesTransition metal
Group10
Period4
Blockd
Appearancelustrous, metallic and
Standard atomic weight58.6934(2) g·mol⁻¹
Electron configuration[Ar] 3d8 4s2
Electrons per shell2, 8, 16, 2

Atomic Properties

Crystal structureface centered cubic
Oxidation states2, 3 (mildly basic oxide)
Electronegativity1.91 (Pauling scale)
Ionization energies1st: 737.1 kJ·mol−1
2nd: 1753.0 kJ·mol−1
3rd: 3395 kJ·mol−1
Atomic radius135 pm
Atomic radius (calc.)149 pm
Covalent radius121 pm
Van der Waals radius163 pm

Physical Properties

Phasesolid
Density (near r.t.)8.908 g·cm−3
Liquid density at m.p.7.81 g·cm−3
Melting point1728 K (1455 °C, 2651 °F)
Boiling point3186 K (2913 °C, 5275 °F)
Critical point
Heat of fusion17.48 kJ·mol−1
Heat of vaporization377.5 kJ·mol−1
Heat capacity(25 °C) 26.07 J·mol−1·K−1

Miscellaneous

Magnetic orderingferromagnetic
Electrical resistivity(20 °C) 69.3 nΩ·m
Thermal conductivity(300 K) 90.9 W·m−1·K−1
Thermal expansion(25 °C) 13.4 µm·m−1·K−1
Speed of sound (thin rod)(r.t.) 4900 m·s−1
Young's modulus200 GPa
Shear modulus76 GPa
Bulk modulus180 GPa
Poisson ratio0.31
Mohs hardness4.0
Vickers hardness638 MPa
Brinell hardness700 MPa