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7 N 14.0067(2)

Nitrogen

Nonmetal
Symbol N
Atomic Number 7
Atomic Weight 14.0067(2)
CAS Registry ID 7727-37-9
Group Name Pnictogen
Period Number 2
Block p-block
State at STP Solid

Description

Sample of Nitrogen ⌕ Enlarge Image

Nitrogen is a non-metal that is a colorless, odorless, gas in its natural state. Nitrogen has an atomic weight of 14.00067, a melting point of -346.18 °F, and a boiling point of -320.42 °F. Some of the more popular uses for nitrogen include: as a component in the formation of ammonia used in fertilizers, as a liquid used to build pressure in crude oil wells to force the oil to the surface, and as a refrigerant to freeze and transport foods.

Isolation

There are three methods that are used to isolate nitrogen. Safety concerns in addiiton to large amounts of commercially available nitrogen make laboratory isolation rare and unnecessary.

Nitrogen ⌕ Enlarge Image

Large amounts of pure nitrogen are isolated through factional distillation. This is the most common massive scale production method of pure nitrogen. Nitrogen gas is the largest component, up to 78%, of the air that we breathe. To extract pure nitrogen through fractional distillation, the air is first liquefied than distilled to separate out the nitrogen from the rest of the gases present in the air. Two other methods can be used to obtain nitrogen, but these reactions can be hazardous and should only be performed by professions. The first method involves heating sodium azide to 572 °F to produce two parts of sodium to three parts of pure nitrogen gas. The second method involves heating ammonium dichromate to produce pure nitrogen gas, Cr203, and water. Commercial amounts of nitrogen can also be collected as a by-product of processing industrial concentrations of oxygen through the air. Pure nitrogen, liquid and gas, is dangerous and needs to be handled with care.

General

NameNitrogen
SymbolN
Number7
Chemical seriesNonmetal
Group15
Period2
Blockp
Appearancecolorless gas
Standard atomic weight14.0067(2) g·mol⁻¹
Electron configuration1s2 2s2 2p3
Electrons per shell2, 5

Atomic Properties

Crystal structurehexagonal
Oxidation states±3, 5, 4, 2 (strongly acidic oxide)
Electronegativity3.04 (Pauling scale)
Ionization energies1st: 1402.3 kJ·mol−1
2nd: 2856 kJ·mol−1
3rd: 4578.1 kJ·mol−1
Atomic radius65 pm
Atomic radius (calc.)56 pm
Covalent radius75 pm
Van der Waals radius

Physical Properties

Phasegas
Density (near r.t.)(0 °C, 101.325 kPa) 1.251 g/L
Liquid density at m.p.
Melting point63.15 K (-210.00 °C, -346.00 °F)
Boiling point77.36 K (-195.79 °C, -320.42 °F)
Critical point126.21 K, 3.39 MPa
Heat of fusion(N2) 0.720 kJ·mol−1
Heat of vaporization(N2) 5.57 kJ·mol−1
Heat capacity(25 °C) (N2) 29.124 J·mol−1·K−1

Miscellaneous

Magnetic orderingdiamagnetic
Electrical resistivity
Thermal conductivity(300 K) 25.83 × 10−3 W·m−1·K−1
Thermal expansion
Speed of sound (thin rod)(gas, 27 °C) 353 m/s
Young's modulus
Shear modulus
Bulk modulus
Poisson ratio
Mohs hardness
Vickers hardness
Brinell hardness