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8 O 15.9994(3)

Oxygen

nonmetals, chalcogens
Symbol O
Atomic Number 8
Atomic Weight 15.9994(3)
CAS Registry ID 7782-44-7
Group Name Chalcogen
Period Number 2
Block p-block
State at STP Solid

Description

Sample of Oxygen ⌕ Enlarge Image

Oxygen is a non-metal that is in the form of a colorless gas in its natural state. Oxygen has an atomic weight of 15.9995, a melting point of -360.9 °F, and a boiling point of -297.2 °F. Oxygen is necessary for life for almost all organisms on the earth, and oxygen forms the ozone layer around the earth that protects against ultraviolet rays against the sun. Industrial uses of oxygen include: as a respiration aid for ill persons, as a component in rocket fuel, the manufacture of steel, and in chemical reactions to create methanol.

Isolation

There are two main methods that are used to isolate pure oxygen for industrial uses. Additional methods are used as well, but some of these isolation procedures are not energy efficient.

Oxygen ⌕ Enlarge Image

The two main methods used to isolate oxygen are through fractional distillation and through the use of zeolite molecular sieves. The process of fractional distillation involves liquefying the air and distilling out nitrogen as a vapor leaving liquid oxygen. The second method of isolation involves passing dry, clean, air through a bed of zeolite molecular sieves. The sieves absorb nitrogen gas leaving a purity of oxygen gas at 90 – 93%. Additional processes used to isolate oxygen include: electrolysis of water to separate oxygen from hydrogen, using chemical catalysts like chemical oxygen generators, and through non-cryogenic methods through pressure swing adsorption and vacuum-pressure swing adsorption. Another method of oxygen isolation involves using high pressure, or electrical currents, to force air through ceramic membranes composed of zirconium oxide. Chemical catalysts are used in chemical oxygen generators to isolate and release oxygen for use by astronauts, firefighters, and rescue workers; the source of oxygen from these generators is from inorganic chlorates, perchlorates, or superoxides.

General

NameOxygen
SymbolO
Number8
Chemical seriesnonmetals, chalcogens
Group16
Period2
Blockp
Appearancecolorless (gas)
Standard atomic weight15.9994(3) g·mol⁻¹
Electron configuration1s2 2s2 2p4
Electrons per shell2, 6

Atomic Properties

Crystal structurecubic
Oxidation states−2, −1 (neutral oxide)
Electronegativity3.44 (Pauling scale)
Ionization energies1st: 1313.9 kJ·mol−1
2nd: 3388.3 kJ·mol−1
3rd: 5300.5 kJ·mol−1
Atomic radius60 pm
Atomic radius (calc.)48 pm
Covalent radius73 pm
Van der Waals radius152 pm

Physical Properties

Phasegas
Density (near r.t.)(0 °C, 101.325 kPa) 1.429 g/L
Liquid density at m.p.
Melting point54.36 K (-218.79 °C, -361.82 °F)
Boiling point90.20 K (-182.95 °C, -297.31 °F)
Critical point154.59 K, 5.043 MPa
Heat of fusion(O2) 0.444 kJ·mol−1
Heat of vaporization(O2) 6.82 kJ·mol−1
Heat capacity(25 °C) (O2) 29.378 J·mol−1·K−1

Miscellaneous

Magnetic orderingparamagnetic
Electrical resistivity
Thermal conductivity(300 K) 26.58 m W·m−1·K−1
Thermal expansion
Speed of sound (thin rod)(gas, 27 °C) 330 m/s
Young's modulus
Shear modulus
Bulk modulus
Poisson ratio
Mohs hardness
Vickers hardness
Brinell hardness