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78 Pt 195.084(9)

Platinum

Transition metal
Symbol Pt
Atomic Number 78
Atomic Weight 195.084(9)
CAS Registry ID 7440-06-4
Group Name Precious metal
Period Number 6
Block d-block
State at STP Solid

Description

Sample of Platinum ⌕ Enlarge Image

Platinum is a lustrous, grey white, transition metal in its natural solid state. It is resistant to corrosion and has strong catalytic properties. Platinum has an atomic weight of 195.084, a melting point of 3214.9 °F, and a boiling point of 6917 °F. Some common uses of platinum include: as a catalyst component in catalytic converters and fuel cells, in the form of electrodes for electrolytic reactions, as a component in precious jewelry, as a catalyst in glow plugs, and as a component for certain types of photography.

Isolation

Platinum does occur in its free state in nature, but it is very rare. Isolation processes can be used to isolate platinum from such minerals as iridium and platiniridium.

Platinum ⌕ Enlarge Image

As a rare and precious metal, platinum is only extracted and isolated on a commercial basis; small scale laboratory isolation of platinum is too expensive and energetically inefficient. The isolation process of platinum begins with treating the ore it occurs in with a mixture of hydrochloric acid and nitric acid. This results in a solution which contains any gold and palladium complexes in the mineral, in addition to a hydrogen platinum chorine compound. Iron chloride is added to the solution to precipitate out any gold; impure platinum is removed by treating the solution with ammonium chloride in the form of a precipitate. The impure precipitate compound containing platinum is then burned resulting in a platinum sponge which contains impurities. Further platinum isolation is carried out by treating the sponge with a mixture of hydrochloric acid and nitric acid; sodium bromated removes additional impurities, and the resulting product is treated with ammonium hydroxide and then burned which yields pure platinum metal isolation.

General

NamePlatinum
SymbolPt
Number78
Chemical seriesTransition metal
Group10
Period6
Blockd
Appearancegrayish white
Standard atomic weight195.084(9) g·mol⁻¹
Electron configuration[Xe] 4f14 5d9 6s1
Electrons per shell2, 8, 18, 32, 17, 1

Atomic Properties

Crystal structurecubic face centered
Oxidation states1, 2, 3, 4, 5, 6 (mildly basic oxide)
Electronegativity2.28 (scale Pauling)
Ionization energies1st: 870 kJ/mol
2nd: 1791 kJ/mol
Atomic radius135 pm
Atomic radius (calc.)177 pm
Covalent radius128 pm
Van der Waals radius175 pm

Physical Properties

Phasesolid
Density (near r.t.)21.45  g·cm−3
Liquid density at m.p.19.77  g·cm−3
Melting point2041.4 K (1768.3 °C, 3214.9 °F)
Boiling point4098 K (3825 °C, 6917 °F)
Critical point
Heat of fusion22.17  kJ·mol−1
Heat of vaporization469  kJ·mol−1
Heat capacity(25 °C) 25.86  J·mol−1·K−1

Miscellaneous

Magnetic orderingparamagnetic
Electrical resistivity(20 °C) 105 n Ω·m
Thermal conductivity(300 K) 71.6  W·m−1·K−1
Thermal expansion(25 °C) 8.8  µm·m−1·K−1
Speed of sound (thin rod)(r.t.) 2800  m·s−1
Young's modulus168 GPa
Shear modulus61 GPa
Bulk modulus230 GPa
Poisson ratio0.38
Mohs hardness4 - 4.5
Vickers hardness549 MPa
Brinell hardness392 MPa