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84 p (209)

Polonium

Metalloid
Symbol p
Atomic Number 84
Atomic Weight (209)
CAS Registry ID 7440-08-6
Group Name Chalcogen
Period Number 6
Block p-block
State at STP Solid

Description

Sample of Polonium ⌕ Enlarge Image

Polonium is a metalloid that is silver colored solid in its natural solid state. Polonium is highly radioactive and extremely unstable. Polonium has an atomic weight of 209, a melting point of 489 °F, and a boiling point of 1764 °F. Polonium does not have many uses due to its radioactivity. Some of the few uses of polonium include: as an alloy for a source of neutrons, as an atomic heat source, and sometimes it is used as a poison.

Isolation

Polonium is extremely rare, and it is normally only found and isolated in small amounts from ores which also contain uranium.

Polonium ⌕ Enlarge Image

The isolation process of polonium can never be carried out in a small scale laboratory setting as this element is extremely toxic and radioactive. Polonium is also very rare. Most isolation procedures are carried out from ore which contains bismuth and uranium. The bismuth and uranium are separated, and then the polonium must be separated from the bismuth. These processes are carried out through fractional distillation or through using silver and the process of electro-depositing to separate the bismuth from the polonium. Fractional distillation of these two elements relies of the different boiling points of the elements in order to heat them to temperatures in which one element is boiled off while the other element remains. Special compartments collect the gas of the vaporized element in order to condense the element back into a liquid and then solid state. Polonium can also be produced through neutron irradiation of the bismuth isotope 209.

General

NamePolonium
Symbolp
Number84
Chemical seriesMetalloid
Group16
Period6
Blockp
Appearancesilvery
Standard atomic weight(209) g·mol⁻¹
Electron configuration[Xe] 6s2 4f14 5d10 6p4
Electrons per shell2, 8, 18, 32, 18, 6

Atomic Properties

Crystal structurecubic
Oxidation states4, 2 (amphoteric oxide)
Electronegativity2.0 (scale Pauling)
Ionization energies1st: 812.1 kJ/mol
Atomic radius190  pm
Atomic radius (calc.)135  pm
Covalent radius
Van der Waals radius

Physical Properties

Phasesolid
Density (near r.t.)(alpha) 9.196  g·cm−3
Liquid density at m.p.
Melting point527 K (254 °C, 489 °F)
Boiling point1235 K (962 °C, 1764 °F)
Critical point
Heat of fusionca. 13  kJ·mol−1
Heat of vaporization102.91  kJ·mol−1
Heat capacity(25 °C) 26.4  J·mol−1·K−1

Miscellaneous

Magnetic orderingnonmagnetic
Electrical resistivity(0 °C) (α) 0.40 µΩ·m
Thermal conductivity(300 K) ? 20  W·m−1·K−1
Thermal expansion(25 °C) 23.5  µm·m−1·K−1
Speed of sound (thin rod)
Young's modulus
Shear modulus
Bulk modulus
Poisson ratio
Mohs hardness
Vickers hardness
Brinell hardness