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61 Pm [145](0)

Promethium

Lanthanide
Symbol Pm
Atomic Number 61
Atomic Weight [145](0)
CAS Registry ID 7440-12-2
Group Name Lanthanoid
Period Number 6
Block f-block
State at STP Solid

Description

Sample of Promethium ⌕ Enlarge Image

Promethium is a lanthanide that has a bright metallic color in its natural solid state. It is a radioactive element, and the salts of promethium will glow in the dark a light blue or greenish color because of the radioactive characteristics. Promethium has an atomic weight of 145, a melting point of 1908 °F, and a boiling point of 5432 °F. Some common uses of promethium include: as a source for beta radiation, as a component in nuclear batteries, and as a light source for signals to operate independently.

Isolation

Promethium is very rarely found in pitchblende; it is also formed as a by product of uranium fission. Isolation or promethium can be used to collect it for commercial uses.

Promethium ⌕ Enlarge Image

Promethium is not normally extracted from pitchblende as it has only been found in this mineral very rarely. Pitchblende is another name for the mineral uraninite which contains uranium oxide, lead, thorium, and rare earth elements. As promethium is a lanthanide, it is possible to isolate it from pitchblende using similar processes that are used to separate lanthanides from the minerals they occur in. The process would have to involve treatment of the uraninite with sulphuric acid, hydrochloric acid, and sodium hydroxide to extract the lanthanides in their salt form. Further processing using solvent extractions and ion exchange chromatography would isolate promethium as a fluoride form. A heated reaction with calcium would yield pure promethium.

Pure promethium is normally collected as a by production from uranium fission. The process of uranium fission involves slitting the uranium atom to form ‘fission.’ Pure promethium must be handled with extreme caution as it has strong radioactive characteristics.

General

NamePromethium
SymbolPm
Number61
Chemical seriesLanthanide
Groupn/a
Period6
Blockf
Appearancemetallic
Standard atomic weight[145](0) g·mol⁻¹
Electron configuration[Xe] 4f5 6s2
Electrons per shell2, 8, 18, 23, 8, 2

Atomic Properties

Crystal structurehexagonal
Oxidation states3 (mildly basic oxide)
Electronegativity? 1.13 (scale Pauling)
Ionization energies1st:  540  kJ·mol−1
2nd:  1050  kJ·mol−1
3rd:  2150  kJ·mol−1
Atomic radius185  pm
Atomic radius (calc.)205  pm
Covalent radius
Van der Waals radius

Physical Properties

Phasesolid
Density (near r.t.)7.26  g·cm−3
Liquid density at m.p.
Melting point1315 K (1042 °C, 1908 °F)
Boiling point3273 K (3000 °C, 5432 °F)
Critical point
Heat of fusion7.13  kJ·mol−1
Heat of vaporization289  kJ·mol−1
Heat capacity

Miscellaneous

Magnetic ordering
Electrical resistivity(r.t.) est. 0.75 µΩ·m
Thermal conductivity(300 K) 17.9  W·m−1·K−1
Thermal expansion(r.t.) (α, poly) est. 11 µm/(m·K)
Speed of sound (thin rod)
Young's modulus(α form) est. 46  GPa
Shear modulus(α form) est. 18  GPa
Bulk modulus(α form) est. 33  GPa
Poisson ratio(α form) est. 0.28
Mohs hardness
Vickers hardness
Brinell hardness