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37 Rb 85.4678(3)

Rubidium

Alkali metal
Symbol Rb
Atomic Number 37
Atomic Weight 85.4678(3)
CAS Registry ID 7440-17-7
Group Name Alkali metal
Period Number 5
Block s-block
State at STP Solid

Description

Sample of Rubidium ⌕ Enlarge Image

Rubidium is an alkali metal that is a shiny grey white solid in its natural state. Rubidium is a very soft metal that oxidizes easily in air. Rubidium has an atomic weight of 85.4673, a melting point of 102.76 °F, and a boiling point of 1270 °F. Some common uses of rubidium include: as a fluid in vapor turbines, as a component in photocells and atomic clocks, as a component in certain types of glass, and in the production of super oxides.

Isolation

Rubidium is most often found in nature in minerals such as leucite, pollucite, and zinnwaldite; all of these minerals contain a small percent of rubidium oxide.

Rubidium ⌕ Enlarge Image

Isolation procedures that are used to extract rubidium from mineral ores most often use the ore lepidolite as this ore has the highest concentration of rubidium, (approximately 1.5%), out of all the rubidium ores. Rubidium can also be isolated from potassium minerals and potassium chlorides that contain rubidium. The metal form of rubidium is isolated by reducing rubidium chloride with calcium.

Rubidium chloride can also be reduced with metallic sodium. This isolation process of rubidium requires an electrolytic step because rubidium has poor electronegative properties. In the electrolytic step, the cathode rubidium is reacted with the anode chloride; hot molten rubidium chloride can only be reacted with pure metallic sodium. If the sodium is in the form of a salt, the rubidium chloride cannot be isolated as it will be too soluble in this process. The reaction between sodium and rubidium chloride results in pure rubidium and sodium chloride compounds.

General

NameRubidium
SymbolRb
Number37
Chemical seriesAlkali metal
Group1
Period5
Blocks
Appearancegrey white
Standard atomic weight85.4678(3) g·mol⁻¹
Electron configuration[Kr] 5s1
Electrons per shell2, 8, 18, 8, 1

Atomic Properties

Crystal structurecubic body centered
Oxidation states1 (strongly basic oxide)
Electronegativity0.82 (scale Pauling)
Ionization energies1st:  403.0  kJ·mol−1
2nd:  2633  kJ·mol−1
3rd:  3860  kJ·mol−1
Atomic radius235 pm
Atomic radius (calc.)265 pm
Covalent radius211 pm
Van der Waals radius244 pm

Physical Properties

Phasesolid
Density (near r.t.)1.532  g·cm−3
Liquid density at m.p.1.46  g·cm−3
Melting point312.46 K (39.31 °C, 102.76 °F)
Boiling point961 K (688 °C, 1270 °F)
Critical point(extrapolated) 2093 K, 16 MPa
Heat of fusion2.19  kJ·mol−1
Heat of vaporization75.77  kJ·mol−1
Heat capacity(25 °C) 31.060  J·mol−1·K−1

Miscellaneous

Magnetic ordering
Electrical resistivity(20 °C) 128 n Ω·m
Thermal conductivity(300 K) 58.2  W·m−1·K−1
Thermal expansion
Speed of sound (thin rod)(20 °C) 1300 m/s
Young's modulus2.4  GPa
Shear modulus
Bulk modulus2.5  GPa
Poisson ratio
Mohs hardness0.3
Vickers hardness
Brinell hardness0.216  MPa