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73 Ta 180.94788(2)

Tantalum

Transition metal
Symbol Ta
Atomic Number 73
Atomic Weight 180.94788(2)
CAS Registry ID 7440-25-7
Group Name (none)
Period Number 6
Block d-block
State at STP Solid

Description

Sample of Tantalum ⌕ Enlarge Image

Tantalum is one of the transition metals that has a grayish blue color in its natural solid state. It is resistant to corrosion and conducts heat and electricity well. Tantalum has an atomic weight of 180.94788, a melting point of 5463 °F, and a boiling point of 9856 °F. Tantalum is most commonly used in a powder in the manufacture process of electronic components. It is also used in some metal alloys and super alloys, and as a component on surgical instruments and implants.

Isolation

Tantalum is not found in its free state in nature, and isolation procedures are needed to extract it from compounds that it occurs in.

Tantalum ⌕ Enlarge Image

Some of the minerals that tantalum is found in include euxenite, microlite, and tantalite. It also occurs in columbite in the ore coltan. The isolation process of tantalum is complex as it often occurs with niobium; the similar chemical traits of these elements makes extraction difficult and impossible to perform in a small laboratory. Commercial reduction, extraction, and isolation of tantalum from niobium involves several steps.

During tantalum isolation processing, the ore is first fused with an alkali; the resulting tantalum compound is extracted using a mixture of hydrofluoric acid. The acidic solution that is formed undergoes a liquid-liquid extraction process in order to extract tantalum salts into a ketone complex named MIBK; this extraction process removes tantalum from the niobium as niobium remains in the solution. The tantalum compound is then converted into an oxide and reduced through sodium or carbon. Tantalum is also often isolated as a by product from tin processing using smelting.

General

NameTantalum
SymbolTa
Number73
Chemical seriesTransition metal
Group5
Period6
Blockd
Appearancegray blue
Standard atomic weight180.94788(2) g·mol⁻¹
Electron configuration[Xe] 4f14 5d3 6s2
Electrons per shell2, 8, 18, 32, 11, 2

Atomic Properties

Crystal structurecubic body centered
Oxidation states5, 4, 3 (mildly acidic oxide)
Electronegativity1.5 (scale Pauling)
Ionization energies1st: 761 kJ/mol
2nd: 1500 kJ/mol
Atomic radius145  pm
Atomic radius (calc.)200 pm
Covalent radius138 pm
Van der Waals radius

Physical Properties

Phasesolid
Density (near r.t.)16.69  g·cm−3
Liquid density at m.p.15  g·cm−3
Melting point3290 K (3017 °C, 5463 °F)
Boiling point5731 K (5458 °C, 9856 °F)
Critical point
Heat of fusion36.57  kJ·mol−1
Heat of vaporization732.8  kJ·mol−1
Heat capacity(25 °C) 25.36  J·mol−1·K−1

Miscellaneous

Magnetic ordering
Electrical resistivity(20 °C) 131 n Ω·m
Thermal conductivity(300 K) 57.5  W·m−1·K−1
Thermal expansion(25 °C) 6.3  µm·m−1·K−1
Speed of sound (thin rod)(20 °C) 3400 m/s
Young's modulus186 GPa
Shear modulus69 GPa
Bulk modulus200 GPa
Poisson ratio0.34
Mohs hardness6.5
Vickers hardness873 MPa
Brinell hardness800 MPa