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43 Tc [98](0)

Technetium

Transition metal
Symbol Tc
Atomic Number 43
Atomic Weight [98](0)
CAS Registry ID 7440-26-8
Group Name (none)
Period Number 5
Block d-block
State at STP Solid

Description

Sample of Technetium ⌕ Enlarge Image

Technetium is a transition metal that is a bright, shiny, silvery grey metal in its natural solid state. There are no stable isotopes of technetium, and it is a radioactive element. Technetium has an atomic weight of 98, a melting point of 3915 °F, and a boiling point of 7709 °F. Some common uses of technetium include: as a radioactive isotope used in a variety of medical tests, as a catalysts in certain chemical reactions, and as a superconductor in extreme temperatures.

Isolation

The isolation of technetium is only performed in special laboratories due the radioactive properties of the element; there are two ways in which technetium can be isolated.

Technetium ⌕ Enlarge Image

Technetium is a highly unstable element, and so it is only found very rarely in minute quantities in the earth’s crust; these small amounts present in the earth’s crust are created as a byproduct from the spontaneous fission of uranium. Most of the technetium on the earth is produced, and isolated, in large quantities as fission waste in spent nuclear fuel rods; due to the radioactive properties of this element, the tons of technetium that are produced each year from nuclear reactors cannot yet be used for large scale commercial purposes.

One another reaction can be used to isolate technetium. This reaction uses the sulfide form of technetium, or the pertechnate form of technetium, and reacts it with hydrogen under heated conditions. During this isolation reaction, either Tc2S7, or NH4TcO4, is reacted with hydrogen and heated to 2012 °F. While this isolation reaction is effective, it is not normally used as so much technetium is produced from nuclear reactors.

General

NameTechnetium
SymbolTc
Number43
Chemical seriesTransition metal
Group7
Period5
Blockd
Appearancesilvery gray metal
Standard atomic weight[98](0) g·mol⁻¹
Electron configuration[Kr] 4d5 5s2
Electrons per shell2, 8, 18, 13, 2

Atomic Properties

Crystal structurehexagonal
Oxidation states7 (strongly acidic oxide)
Electronegativity1.9 (scale Pauling)
Ionization energies1st: 702 kJ/mol
2nd: 1470 kJ/mol
3rd: 2850 kJ/mol
Atomic radius135 pm
Atomic radius (calc.)185 pm
Covalent radius156 pm
Van der Waals radius

Physical Properties

Phasesolid
Density (near r.t.)11  g·cm−3
Liquid density at m.p.
Melting point2430 K (2157 °C, 3915 °F)
Boiling point4538 K (4265 °C, 7709 °F)
Critical point
Heat of fusion33.29  kJ·mol−1
Heat of vaporization585.2  kJ·mol−1
Heat capacity(25 °C) 24.27  J·mol−1·K−1

Miscellaneous

Magnetic orderingParamagnetic
Electrical resistivity
Thermal conductivity(300 K) 50.6  W·m−1·K−1
Thermal expansion
Speed of sound (thin rod)
Young's modulus
Shear modulus
Bulk modulus
Poisson ratio
Mohs hardness
Vickers hardness
Brinell hardness