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52 Te 127.60(3)

Tellurium

Metalloid
Symbol Te
Atomic Number 52
Atomic Weight 127.60(3)
CAS Registry ID 13494-80-9
Group Name Chalcogen
Period Number 5
Block p-block
State at STP Solid

Description

Sample of Tellurium ⌕ Enlarge Image

Tellurium is a metalloid with a shiny sliver grey color in its natural solid state. Tellurium is one of the rarest element on earth, and it is a brittle metal that has semi-conductive traits. Tellurium has an atomic weight of 127.60, a melting point of 841.12 °F, and a boiling point of 1810 °F. Tellurium metal is commonly used in alloys to strengthen lead and increase the workability of stainless steel and copper; it is also used in ceramics, and as a semiconductor.

Isolation

As a rare substance, tellurium is usually only isolated on a commercial basis. The isolation process used depends on which compounds are present with the tellurium.

Tellurium ⌕ Enlarge Image

Tellurium does exist in nature in its free form, but it is very rarely found this way. Most tellurium in nature occurs in nature and gold tellurides such as calaverite, krennerite, petzite, and sylvanite. Additional sources of tellurium can be used for isolation. One isolation process uses treatment of copper ore; this treatment process using electrolytic refining of copper forms anode sludges of tellurium. Tellurium can also be collected and isolated from dust that is emitted from the process of refining lead using a blast furnace.

Another isolation method which extracts tellurium from copper uses a multi-step chemical reaction process. The first step of the isolation process is to oxidize the tellurium-copper complex using sodium carbonate and oxygen to produce tellurite. The tellurite is then acidified with sulphuric acid to precipitate out of the solution in its dioxide form. The tellurium dioxide is then dissolved in sodium hydroxide, and electrolytic reduction is used to produce pure tellurium.

General

NameTellurium
SymbolTe
Number52
Chemical seriesMetalloid
Group16
Period5
Blockp
Appearancesilvery lustrous gray
Standard atomic weight127.60(3) g·mol⁻¹
Electron configuration[Kr] 5s2 4d10 5p4
Electrons per shell2, 8, 18, 18, 6

Atomic Properties

Crystal structurehexagonal
Oxidation states±2, 4, 6 (mildly acidic oxide)
Electronegativity2.1 (scale Pauling)
Ionization energies1st:  869.3  kJ·mol−1
2nd:  1790  kJ·mol−1
3rd:  2698  kJ·mol−1
Atomic radius140 pm
Atomic radius (calc.)123 pm
Covalent radius135 pm
Van der Waals radius206 pm

Physical Properties

Phasesolid
Density (near r.t.)6.24  g·cm−3
Liquid density at m.p.5.70  g·cm−3
Melting point722.66 K (449.51 °C, 841.12 °F)
Boiling point1261 K (988 °C, 1810 °F)
Critical point
Heat of fusion17.49  kJ·mol−1
Heat of vaporization114.1  kJ·mol−1
Heat capacity(25 °C) 25.73  J·mol−1·K−1

Miscellaneous

Magnetic orderingnonmagnetic
Electrical resistivity
Thermal conductivity(300 K) (1.97–3.38)  W·m−1·K−1
Thermal expansion
Speed of sound (thin rod)(20 °C) 2610 m/s
Young's modulus43 GPa
Shear modulus16 GPa
Bulk modulus65 GPa
Poisson ratio
Mohs hardness2.25
Vickers hardness
Brinell hardness180 MPa