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81 Tl 204.3833(2)

Thallium

Poor metal
Symbol Tl
Atomic Number 81
Atomic Weight 204.3833(2)
CAS Registry ID 7440-28-0
Group Name (none)
Period Number 6
Block p-block
State at STP Solid

Description

Sample of Thallium ⌕ Enlarge Image

Thallium is one the poor metals that has a bright, silvery white, color in its natural solid state. It is a soft and malleable poor metal, and it is highly toxic. Thallium has an atomic weight of 204.3833, a melting point of 579°F, and a boiling point of 2683 °F. Some common uses of thallium include: as a component in photo cells, as a component in infrared optical materials, in the manufacture of certain types of glasses, and as a component in equipment used to detect gamma radiation.

Isolation

Thallium is not found freely in nature, and needs to be isolated from the compounds it occurs in. A number of isolation methods can be used.

Thallium ⌕ Enlarge Image

Due to the toxicity of thallium, the isolation procedures needed to extract it from the compounds it occurs in are not normally carried out on a small scale laboratory basis. Instead, thallium is extracted from certain sources on a commercial basis. While thallium occurs in clays, soils, and granites it is not isolated from these compounds as the procedures are too expensive. The most widely used isolation procedures for thallium commercial needs are from small amounts that are found in copper, lead, sulfide ores, and zinc.

The smelting process carried out on lead and zinc ores can be used to recover thallium. The smelting process is a form of chemical reduction that uses extractive metallurgy to isolate elements that occur in the same compounds from one another. Thallium can also be isolated as a byproduct of roasting pyrites for sulfuric acid recovery. Pure thallium must be handled with extreme caution due to its toxicity and cancer causing characteristics.

General

NameThallium
SymbolTl
Number81
Chemical seriesPoor metal
Group13
Period6
Blockp
Appearancesilvery white
Standard atomic weight204.3833(2) g·mol⁻¹
Electron configuration[Xe] 4f14 5d10 6s2 6p1
Electrons per shell2, 8, 18, 32, 18, 3

Atomic Properties

Crystal structurehexagonal
Oxidation states3, 1 (mildly basic oxide)
Electronegativity1.62 (scale Pauling)
Ionization energies1st: 589.4 kJ/mol
2nd: 1971 kJ/mol
3rd: 2878 kJ/mol
Atomic radius190 pm
Atomic radius (calc.)156 pm
Covalent radius148 pm
Van der Waals radius196 pm

Physical Properties

Phasesolid
Density (near r.t.)11.85  g·cm−3
Liquid density at m.p.11.22  g·cm−3
Melting point577 K (304 °C, 579 °F)
Boiling point1746 K (1473 °C, 2683 °F)
Critical point
Heat of fusion4.14  kJ·mol−1
Heat of vaporization165  kJ·mol−1
Heat capacity(25 °C) 26.32  J·mol−1·K−1

Miscellaneous

Magnetic ordering
Electrical resistivity(20 °C) 0.18 µ Ω·m
Thermal conductivity(300 K) 46.1  W·m−1·K−1
Thermal expansion(25 °C) 29.9  µm·m−1·K−1
Speed of sound (thin rod)(20 °C) 818 m/s
Young's modulus8 GPa
Shear modulus2.8 GPa
Bulk modulus43 GPa
Poisson ratio0.45
Mohs hardness1.2
Vickers hardness
Brinell hardness26.4 MPa