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90 Th 232.03806(2)

Thorium

Actinoid
Symbol Th
Atomic Number 90
Atomic Weight 232.03806(2)
CAS Registry ID 7440-29-1
Group Name Actinoid
Period Number 7
Block f-block
State at STP Solid

Description

Sample of Thorium ⌕ Enlarge Image

Thorium is an actinide that is a silvery white solid in its natural solid state. It has slight radioactive characteristics, and it has the longest liquid range of all known elements. Thorium has an atomic weight of 232.03806, a melting point of 3348 °F, and a boiling point of 8650 °F. Some common uses of thorium include: as an alloy with magnesium for aircraft, as a component in tungsten wire, as a component in material used to produce nuclear fuel, and as a radiation shield.

Isolation

Thorium is a commonly found element and occurs in many rocks and soils. It is usually isolated from certain minerals.

Thorium ⌕ Enlarge Image

The isolation processes of thorium are usually carried out on minerals such as thorium phosphate and monazite. Monazite can carry as much as 21% thorium in its structure, and it is the main ore that is used for thorium extraction and isolation. Processing thorium from monazite is a complex process, and so it is hardly ever isolated on a small scale laboratory basis. This process begins with extracting monazite sand and then dissolving it in an inorganic acid, mainly sulfuric acid. Next, the thorium is extracted from the solution using an amine compound. The extracted complex of thorium is then treated to an anion compound such as a chloride or hydroxide; this step dissolves the thorium out in a liquid phase. Precipitation of the thorium is used to further isolate it. Isolated thorium needs to be handled with caution even though the levels of radiation it emits cannot penetrate skin.

General

NameThorium
SymbolTh
Number90
Chemical seriesActinoid
Groupn/a
Period7
Blockf
Appearancesilvery white
Standard atomic weight232.03806(2) g·mol⁻¹
Electron configuration[Rn] 6d2 7s2
Electrons per shell2, 8, 18, 32, 18, 10, 2

Atomic Properties

Crystal structurecubic face centered
Oxidation states4 (weakly basic oxide)
Electronegativity1.3 (scale Pauling)
Ionization energies1st:  587  kJ·mol−1
2nd:  1110  kJ·mol−1
3rd:  1930  kJ·mol−1
Atomic radius180  pm
Atomic radius (calc.)
Covalent radius
Van der Waals radius

Physical Properties

Phasesolid
Density (near r.t.)11.7  g·cm−3
Liquid density at m.p.
Melting point2115 K (1842 °C, 3348 °F)
Boiling point5061 K (4788 °C, 8650 °F)
Critical point
Heat of fusion13.81  kJ·mol−1
Heat of vaporization514  kJ·mol−1
Heat capacity(25 °C) 26.230  J·mol−1·K−1

Miscellaneous

Magnetic ordering
Electrical resistivity(0 °C) 147 nΩ·m
Thermal conductivity(300 K) 54.0  W·m−1·K−1
Thermal expansion(25 °C) 11.0  µm·m−1·K−1
Speed of sound (thin rod)(20 °C) 2490 m/s
Young's modulus79 GPa
Shear modulus31 GPa
Bulk modulus54 GPa
Poisson ratio0.27
Mohs hardness3.0
Vickers hardness350 MPa
Brinell hardness400 MPa