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92 U 238.02891(3)

Uranium

Actinoid
Symbol U
Atomic Number 92
Atomic Weight 238.02891(3)
CAS Registry ID 7440-61-1
Group Name Actinoid
Period Number 7
Block f-block
State at STP Solid

Description

Sample of Uranium ⌕ Enlarge Image

Uranium is one of the more popular actinides that has a silver-grey metallic color in its natural solid state. It is has slight radioactive characteristics, is a toxic metal, and it is the densest of all the elements. Uranium has an atomic weight of 238.02891, a melting point of 2070 °F, and a boiling point of 7468 °F. Uranium is often used as a source of energy in nuclear reactors, and it is also used as a colorant in special types of glass.

Isolation

Uranium occurs in many places including different types of rocks, soils, and in some places it is found in water. Isolation processes can be used to extract uranium from these sources.

Uranium ⌕ Enlarge Image

Commercial sources for uranium recovering mainly come from phosphate rock deposits such as the monazite sands. Monazite is the leading source of uranium, along with pitchblende and lignite. Uranium is first collected through either open pit or underground extraction, or through leaching or borehole mining. Most of the uranium ores contain very low amounts of uranium, less than one percent, and the extraction and isolation process is highly complex. First the ores are crushed into a fine powder, then an acid or alkali substance is leached into the powder. This solution is treated to precipitation, solvent extraction, and ion exchange to form ‘yellowcake.’ The cake like product is over ¾ uranium, and it is calcined in order to remove the remaining contaminants. Uranium can also be produced using a variety of methods including: electrolysis of potassium, uranium, fluoride compound, the thermal decomposition of uranium halides, and the reduction of uranium halides with alkaline materials.

General

NameUranium
SymbolU
Number92
Chemical seriesActinoid
Groupn/a
Period7
Blockf
Appearancesilvery gray metallic
Standard atomic weight238.02891(3) g·mol⁻¹
Electron configuration[Rn] 5f3 6d1 7s2
Electrons per shell2, 8, 18, 32, 21, 9, 2

Atomic Properties

Crystal structureorthorhombic
Oxidation states3+,4+,5+,6+[58] (weakly basic oxide)
Electronegativity1.38 (Pauling scale)
Ionization energies1st: 597.6 kJ/mol
2nd: 1420 kJ/mol
Atomic radius175 pm
Atomic radius (calc.)
Covalent radius
Van der Waals radius186 pm

Physical Properties

Phasesolid
Density (near r.t.)19.1 g·cm−3
Liquid density at m.p.17.3 g·cm−3
Melting point1405.3 K (1132.2 °C, 2070 °F)
Boiling point4404 K (4131 °C, 7468 °F)
Critical point
Heat of fusion9.14 kJ·mol−1
Heat of vaporization417.1 kJ·mol−1
Heat capacity(25 °C) 27.665 J·mol−1·K−1

Miscellaneous

Magnetic orderingparamagnetic
Electrical resistivity(0 °C) 0.280 µΩ·m
Thermal conductivity(300 K) 27.5 W·m−1·K−1
Thermal expansion(25 °C) 13.9 µm·m−1·K−1
Speed of sound (thin rod)(20 °C) 3155 m/s
Young's modulus208 GPa
Shear modulus111 GPa
Bulk modulus100 GPa
Poisson ratio0.23
Mohs hardness
Vickers hardness
Brinell hardness