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23 V 50.9415(1)

Vanadium

Transition metal
Symbol V
Atomic Number 23
Atomic Weight 50.9415(1)
CAS Registry ID 7440-62-2
Group Name (none)
Period Number 4
Block d-block
State at STP Solid

Description

Sample of Vanadium ⌕ Enlarge Image

Vanadium is a transition metal that has a silver grey metal color in its natural solid state. It is a soft metal that oxidizes when heated. Vanadium has an atomic weight of 50.9415, a melting point of 3470 °F, and a boiling point of 6165 °F. Some common uses of vanadium include: as ferrovanadium which is a steel additive, as a metallic alloy in the use of surgical tools and rust resistant steels, as a catalyst in the manufacture of sulfuric acid.

Isolation

Vanadium does not occur freely in nature, but is found in a variety of minerals. Different processes can be used to isolate vanadium from these minerals.

Vanadium ⌕ Enlarge Image

Large scale industrial isolation of vanadium for commercial uses does not have to be constructed solely for the purpose of vanadium isolation; most vanadium that is isolated is formed as a byproduct from other industrial chemical processes.

Vanadium ore, or residues gathered as a byproduct, are heated to approximately 1562 °F and reacted with sodium chloride or sodium carbonate; the result of this reaction is sodium vanadate. From this product, vanadium pentoxide is formed by dissolving and acidifying sodium vanadate in water and then heating the solution. Vanadium pentoxide is then reduced through a reaction with calcium to yield pure vanadium.

Another isolation process that can be used to form pure vanadium on a very small scale involves reducing vanadium pentachloride by reacting it with hydrogen or magnesium.

Pure vanadium is not normally produced on a very large scale as ferrovanadium; the main form of ferrovanadium that is used can be produced by reacting vanadium pentoxide with crude iron.

General

NameVanadium
SymbolV
Number23
Chemical seriesTransition metal
Group5
Period4
Blockd
Appearancesilver-grey metal
Standard atomic weight50.9415(1) g·mol⁻¹
Electron configuration[Ar] 3d3 4s2
Electrons per shell2, 8, 11, 2

Atomic Properties

Crystal structurecubic body centered
Oxidation states2, 3, 4, 5 (amphoteric oxide)
Electronegativity1.63 (Pauling scale)
Ionization energies1st: 650.9 kJ·mol−1
2nd: 1414 kJ·mol−1
3rd: 2830 kJ·mol−1
Atomic radius135 pm
Atomic radius (calc.)171 pm
Covalent radius125 pm
Van der Waals radius

Physical Properties

Phasesolid
Density (near r.t.)6.0 g·cm−3
Liquid density at m.p.5.5 g·cm−3
Melting point2183 K (1910 °C, 3470 °F)
Boiling point3680 K (3407 °C, 6165 °F)
Critical point
Heat of fusion21.5 kJ·mol−1
Heat of vaporization459 kJ·mol−1
Heat capacity(25 °C) 24.89 J·mol−1·K−1

Miscellaneous

Magnetic orderingparamagnetic
Electrical resistivity(20 °C) 197 nΩ·m
Thermal conductivity(300 K) 30.7 W·m−1·K−1
Thermal expansion(25 °C) 8.4 µm·m−1·K−1
Speed of sound (thin rod)(20 °C) 4560 m/s
Young's modulus128 GPa
Shear modulus47 GPa
Bulk modulus160 GPa
Poisson ratio0.37
Mohs hardness6.7
Vickers hardness
Brinell hardness