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54 Xe 131.293(6)

Xenon

Noble gas
Symbol Xe
Atomic Number 54
Atomic Weight 131.293(6)
CAS Registry ID 7440-63-3
Group Name Noble gas
Period Number 5
Block p-block
State at STP Solid

Description

Sample of Xenon ⌕ Enlarge Image

Xenon is a colorless, odorless, noble gas. Xenon can be oxidized by strong oxidizing agents, and it emits a blue or lavender glow when exposed to electrical discharge. Xenon has an atomic weight of 131.293, a melting point of - 169.1 °F, and a boiling point of - 162.62 °F. Common uses of xenon include: as a major component in xenon flash lamps and xenon arc lamps, as a starter gas for high pressure sodium lamps, as a component of some lasers, and in general anesthetic.

Isolation

Xenon is found in trace amounts in the earth’s atmosphere; it is also released in gaseous form from some mineral springs. Isolation processes for xenon rely on extracting it out of the air.

Xenon ⌕ Enlarge Image

Xenon is extracted on a large scale for commercial use as a by-product from separating the air into oxygen and nitrogen. Fractional distillation is used in a double column plant to obtain liquid oxygen. The liquid oxygen that is collected from fraction distillation also contains small amounts of krypton and xenon. Further reduction through multiple fractional distillation steps increases the concentration of krypton and xenon in the liquid oxygen. Silica gel is used to absorb the krypton and xenon, or distillation is used to further extract the elements from the oxygen. The final step involves separating the krypton and xenon through distillation using the differing boiling points of the elements. Xenon is stored in its pure form in pressurized metal cylinders. A very small amount of xenon can be produced and isolated from neutron irradiation of fissionable compounds, but this xenon has radioactive properties. Xenon is considered to be non-toxic but many compounds of xenon are toxic.

General

NameXenon
SymbolXe
Number54
Chemical seriesNoble gas
Group18
Period5
Blockp
Appearancecolorless gas
Standard atomic weight131.293(6) g·mol⁻¹
Electron configuration[Kr] 4d10 5s2 5p6
Electrons per shell2, 8, 18, 18, 8

Atomic Properties

Crystal structurecubic face centered
Oxidation states0, +1, +2, +4, +6, +8
Electronegativity2.6 (Pauling scale)
Ionization energies1st: 1170.4 kJ/mol
2nd: 2046.4 kJ/mol
3rd: 3099.4 kJ/mol
Atomic radius
Atomic radius (calc.)108 pm
Covalent radius130 pm
Van der Waals radius216 pm

Physical Properties

Phasegas
Density (near r.t.)(0 °C, 101.325 kPa) 5.894 g/L
Liquid density at m.p.
Melting point(101.325 kPa) 161.4 K (-111.7 °C, -169.1 °F)
Boiling point(101.325 kPa) 165.03 K (-108.12 °C, -162.62 °F)
Critical point289.77 K, 5.841 MPa
Heat of fusion(101.325 kPa) 2.27 kJ·mol−1
Heat of vaporization(101.325 kPa) 12.64 kJ·mol−1
Heat capacity(100 kPa, 25 °C) 20.786 J·mol−1·K−1

Miscellaneous

Magnetic orderingnonmagnetic
Electrical resistivity
Thermal conductivity(300 K) 5.65 m W·m−1·K−1
Thermal expansion
Speed of sound (thin rod)(liquid) 1090 m/s
Young's modulus
Shear modulus
Bulk modulus
Poisson ratio
Mohs hardness
Vickers hardness
Brinell hardness