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70 Yb 173.04(3)

Ytterbium

Lanthanide
Symbol Yb
Atomic Number 70
Atomic Weight 173.04(3)
CAS Registry ID 7440-64-4
Group Name Lanthanoid
Period Number 6
Block f-block
State at STP Solid

Description

Sample of Ytterbium ⌕ Enlarge Image

Ytterbium is a lanthanide that is a silvery white color in its natural solid state. Ytterbium is very soft and can be dissolved in mineral acids; it also reacts slowly with water and oxidizes when exposed to air. Ytterbium has an atomic weight of 173.04, a melting point of 1515 °F, and a boiling point of 2185 °F. Some common uses of ytterbium include: as an alloy for dentistry uses, as a component in solar cells, and in isotope form for radiation sources.

Isolation

Ytterbium does not occur in its free state in nature, but it does occur in mineral compounds with other lanthanides. Isolation procedures are used to extract ytterbium from these sources.

Ytterbium ⌕ Enlarge Image

Ytterbium is extracted on a commercial basis from such minerals as euxenite, monazite, and xenotime. These minerals also contain other rare earth elements or lanthanides that all share similar chemical characteristics with ytterbium. The similarity between the traits of these elements makes extraction and isolation of ytterbium highly complex; the complexity of the extraction process prevents ytterbium from being isolated on a small scale laboratory basis.

The first step of the ytterbium extraction process involves treating the minerals it occurs in with sulfuric acid, hydrochloric acid, and sodium hydroxide. These treatments extract the lanthanide from their mineral compounds in a salt form. Further processing of ytterbium salts using repeated solvent extractions and ion exchange chromatography result in a ytterbium chloride compound. Electrolysis is needed to isolate pure ytterbium from the chlorine. The electrolysis process uses a mixture of molten ytterbium chloride in addition to sodium chloride, and the procedure takes place in a graphite cell.

General

NameYtterbium
SymbolYb
Number70
Chemical seriesLanthanide
Groupn/a
Period6
Blockf
Appearancesilvery white
Standard atomic weight173.04(3) g·mol⁻¹
Electron configuration[Xe] 4f14 6s2
Electrons per shell2, 8, 18, 32, 8, 2

Atomic Properties

Crystal structurecubic face centered
Oxidation states2, 3 (basic oxide)
Electronegativity? 1.1 (scale Pauling)
Ionization energies1st:  603.4  kJ·mol−1
2nd:  1174.8  kJ·mol−1
3rd:  2417  kJ·mol−1
Atomic radius175  pm
Atomic radius (calc.)222  pm
Covalent radius
Van der Waals radius

Physical Properties

Phasesolid
Density (near r.t.)6.90  g·cm−3
Liquid density at m.p.6.21  g·cm−3
Melting point1097 K (824 °C, 1515 °F)
Boiling point1469 K (1196 °C, 2185 °F)
Critical point
Heat of fusion7.66  kJ·mol−1
Heat of vaporization159  kJ·mol−1
Heat capacity(25 °C) 26.74  J·mol−1·K−1

Miscellaneous

Magnetic ordering
Electrical resistivity(r.t.) (β, poly) 0.250 µΩ·m
Thermal conductivity(300 K) 38.5  W·m−1·K−1
Thermal expansion(r.t.) (β, poly) 26.3 µm/(m·K)
Speed of sound (thin rod)(20 °C) 1590 m/s
Young's modulus(β form) 23.9  GPa
Shear modulus(β form) 9.9  GPa
Bulk modulus(β form) 30.5  GPa
Poisson ratio(β form) 0.207
Mohs hardness
Vickers hardness206  MPa
Brinell hardness343  MPa