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39 Y 88.90585(2)

Yttrium

Transition metal
Symbol Y
Atomic Number 39
Atomic Weight 88.90585(2)
CAS Registry ID 7440-65-5
Group Name (none)
Period Number 5
Block d-block
State at STP Solid

Description

Sample of Yttrium ⌕ Enlarge Image

Yttrium is a transition metal that is a silvery white solid in its natural state. It is relatively stable in the air unless it is in small, fine, amounts. Yttrium has an atomic weight of 88.90585, a melting point of 2779 °F, and a boiling point of 6037 °F. Some common uses of yttrium include: as a component in microwave filters, in jewelry as fake diamonds, as a strengthening component in metal alloys, as a catalyst for ethylene polymerization, and in the form of electrodes on high quality spark plugs.

Isolation

Yttrium is never found freely in nature, and isolation procedures are needed to extract pure yttrium from the minerals that it is found in.

Yttrium ⌕ Enlarge Image

Yttrium is almost always found in rare-earth minerals; it is also found in uranium ores, monazite sand, and bastnasite. Yttrium isolation for commercial purposes is usually extracted from monazite and bastnasite. Monazite is a phosphate which contains rare earth metals in addition to yttrium; bastnasite is a carbonate fluoride mineral which contains small amounts of yttrium.

One isolation procedure reduces yttrium fluoride with metal calcium; this reaction results in pure yttrium and calcium fluoride. Another isolation procedure involves extracting salts of yttrium metal present in ores by reactions involving sulphuric acid, followed by hydrochloric acid, followed by sodium hydroxide. Some of the additional isolation procedures that are used involve solvent extraction and ion exchange chromatography. The isolation of yttrium from its ores is a procedure which involves a number of highly complex steps; due to the complexity of isolating yttrium, the extraction of yttrium is hardly ever produced on a small scale laboratory basis.

General

NameYttrium
SymbolY
Number39
Chemical seriesTransition metal
Group3
Period5
Blockd
Appearancesilvery white
Standard atomic weight88.90585(2) g·mol⁻¹
Electron configuration[Kr] 4d1 5s2
Electrons per shell2, 8, 18, 9, 2

Atomic Properties

Crystal structurehexagonal
Oxidation states3 (weakly basic oxide)
Electronegativity1.22 (scale Pauling)
Ionization energies1st:  600  kJ·mol−1
2nd:  1180  kJ·mol−1
3rd:  1980  kJ·mol−1
Atomic radius180  pm
Atomic radius (calc.)212 pm
Covalent radius162 pm
Van der Waals radius

Physical Properties

Phasesolid
Density (near r.t.)4.472  g·cm−3
Liquid density at m.p.4.24  g·cm−3
Melting point1799 K (1526 °C, 2779 °F)
Boiling point3609 K (3336 °C, 6037 °F)
Critical point
Heat of fusion11.42  kJ·mol−1
Heat of vaporization365  kJ·mol−1
Heat capacity(25 °C) 26.53  J·mol−1·K−1

Miscellaneous

Magnetic ordering
Electrical resistivity(r.t.) (α, poly) 596 nΩ·m
Thermal conductivity(300 K) 17.2  W·m−1·K−1
Thermal expansion(r.t.) (α, poly) 10.6 µm/(m·K)
Speed of sound (thin rod)(20 °C) 3300 m/s
Young's modulus63.5  GPa
Shear modulus25.6  GPa
Bulk modulus41.2  GPa
Poisson ratio0.243
Mohs hardness
Vickers hardness
Brinell hardness589  MPa