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30 Zn 65.409(4)

Zinc

Transition metal
Symbol Zn
Atomic Number 30
Atomic Weight 65.409(4)
CAS Registry ID 7440-66-6
Group Name (none)
Period Number 4
Block d-block
State at STP Solid

Description

Sample of Zinc ⌕ Enlarge Image

Zinc is one of the transition metals that is a light blue grey color in its natural solid state; it tarnishes easily in air, and is reactive with acids, alkalis, and other non-metals. Zinc has an atomic weight of 65.409, a melting point of 786. 15 °F, and a boiling point of 1665 °F. Some common uses of zinc include: as an alloy with brass and copper, as a component used to galvanize metals, as a component in dry batteries, and as a component in some monetary coins.

Isolation

Zinc used for commercial purposes has to be separated from zinc minerals and ores. The main zinc isolation procedure used to isolate zinc relies on extractive metallurgy.

Zinc ⌕ Enlarge Image

Zinc isolation begins with the mining of sphalerite minerals which contain zinc sulfides. The froth flotation method is used to gather these minerals. During this process, surfactants and wetting agents are used to separate the sulfides from carbonates and oxides. After the froth flotation procedure, the zinc sulfide is roasted using the process of pyrometallurgy; this process oxideses the zinc sulfide into zinc oxide. Pryometallurgy is the process in which metal ores undergo thermal treatment.

After pyrometallurgy, the zinc oxide produced undergoes under goes a leaching process using sulfuric acid to produce zinc sulfate. During the leaching process, iron and other impurities are removed. The last step of zinc isolation removes such elements as copper, cadmium, and cobalt. Zinc metal is removed from a purified zinc sulfate solution in the form of cathodic deposits that are extracted using electro-winning with aluminum sheets. The electro-winning process is carried out using either a low current density process, or a high currently density process.

General

NameZinc
SymbolZn
Number30
Chemical seriesTransition metal
Group12
Period4
Blockd
Appearancebluish pale gray
Standard atomic weight65.409(4) g·mol⁻¹
Electron configuration[Ar] 3d10 4s2
Electrons per shell2, 8, 18, 2

Atomic Properties

Crystal structurehexagonal
Oxidation states2 (amphoteric oxide)
Electronegativity1.65 (Pauling scale)
Ionization energies1st: 906.4 kJ·mol−1
2nd: 1733.3 kJ·mol−1
3rd: 3833 kJ·mol−1
Atomic radius135 pm
Atomic radius (calc.)142 pm
Covalent radius131 pm
Van der Waals radius139 pm

Physical Properties

Phasesolid
Density (near r.t.)7.14 g·cm−3
Liquid density at m.p.6.57 g·cm−3
Melting point692.68 K (419.53 °C, 787.15 °F)
Boiling point1180 K (907 °C, 1665 °F)
Critical point
Heat of fusion7.32 kJ·mol−1
Heat of vaporization123.6 kJ·mol−1
Heat capacity(25 °C) 25.390 J·mol−1·K−1

Miscellaneous

Magnetic orderingdiamagnetic
Electrical resistivity(20 °C) 59.0 nΩ·m
Thermal conductivity(300 K) 116 W·m−1·K−1
Thermal expansion(25 °C) 30.2 µm·m−1·K−1
Speed of sound (thin rod)(r.t.) (rolled) 3850 m·s−1
Young's modulus108 GPa
Shear modulus43 GPa
Bulk modulus70 GPa
Poisson ratio0.25
Mohs hardness2.5
Vickers hardness
Brinell hardness412 MPa